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Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides
作者:	Culkin, Darcy Ann.
面頁冊數:	285 p.
附註:	Director: John F. Hartwig.
附註:	Source: Dissertation Abstracts International, Volume: 65-03, Section: B, page: 1316.
Contained By:	Dissertation Abstracts International65-03B.
標題:	Chemistry, Inorganic.
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3125179
ISBN:	049672469X

Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides
Culkin, Darcy Ann.

Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides [electronic resource] - 285 p.

Director: John F. Hartwig.

Thesis (Ph.D.)--Yale University, 2004.

A series of arylpalladium alkyl complexes containing varied functional groups alpha to the metal was prepared to reveal the effect of ligand steric and electronic properties on structure, stability, and reactivity. Arylpalladium complexes of methyl, benzyl, enolate, cyanoalkyl, and trifluoroethyl groups underwent carbon-carbon bond-forming reductive elimination upon heating. Mechanistic studies of the reductive elimination process led to the discovery of a new coupling reaction, the palladium-catalyzed alpha-arylation of nitriles, and to the development of improved methods for the palladium-catalyzed synthesis of alpha-aryl amides.

ISBN: 049672469XSubjects--Topical Terms:

197298
Chemistry, Inorganic.

Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides
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