Language:
English
繁體中文
Help
圖資館首頁
Login
Back
Switch To:
Labeled
|
MARC Mode
|
ISBD
Development of synthetic methods for...
~
Kim, Hahn.
Development of synthetic methods for C-O and C-C bond formations via transition metal catalysis.
Record Type:
Electronic resources : Monograph/item
Title/Author:
Development of synthetic methods for C-O and C-C bond formations via transition metal catalysis.
Author:
Kim, Hahn.
Description:
297 p.
Notes:
Adviser: Chulbom Lee.
Notes:
Source: Dissertation Abstracts International, Volume: 68-01, Section: B, page: 0295.
Contained By:
Dissertation Abstracts International68-01B.
Subject:
Chemistry, Organic.
Online resource:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3250017
Development of synthetic methods for C-O and C-C bond formations via transition metal catalysis.
Kim, Hahn.
Development of synthetic methods for C-O and C-C bond formations via transition metal catalysis.
- 297 p.
Adviser: Chulbom Lee.
Thesis (Ph.D.)--Princeton University, 2007.
Recent developments in transition metal catalysis have had a tremendous impact on the science of synthesis. They have allowed conceptually new approaches towards previously unaddressed synthetic problems and have challenged synthetic chemists to imagine unrecognized modes of chemical transformations. The presented thesis aims to exemplify both aspects of these recent developments in transition metal catalysis.Subjects--Topical Terms:
193634
Chemistry, Organic.
Development of synthetic methods for C-O and C-C bond formations via transition metal catalysis.
LDR
:02630nmm _2200265 _450
001
180733
005
20080111103832.5
008
090528s2007 eng d
035
$a
00311759
040
$a
UMI
$c
UMI
100
0
$a
Kim, Hahn.
$3
264315
245
1 0
$a
Development of synthetic methods for C-O and C-C bond formations via transition metal catalysis.
300
$a
297 p.
500
$a
Adviser: Chulbom Lee.
500
$a
Source: Dissertation Abstracts International, Volume: 68-01, Section: B, page: 0295.
502
$a
Thesis (Ph.D.)--Princeton University, 2007.
520
#
$a
Recent developments in transition metal catalysis have had a tremendous impact on the science of synthesis. They have allowed conceptually new approaches towards previously unaddressed synthetic problems and have challenged synthetic chemists to imagine unrecognized modes of chemical transformations. The presented thesis aims to exemplify both aspects of these recent developments in transition metal catalysis.
520
#
$a
The first three chapters deal with the problem of C-O bond formation. Despite its importance, the construction of the C-O bond has not been a trivial synthetic problem. Recognition of this challenge led to the development of a palladium catalyzed allylic etherification method for stereoselective C-O bond formations. Utilizing the zinc(II) ion as the countercation of an alkoxide nucleophile allowed the development of a reliable method to construct alpha,alpha' stereogenic ether linkages for the first time. Extension of this chemistry into the carbohydrate area demonstrated the first report of a reagent controlled stereoselective glycosylation of glycals.
520
#
$a
The latter three chapters deal with discovering new modes of C-C bond formation with utilization of metal vinylidene catalysis. Metal vinylidenes are organometallic intermediates with unique structures and reactivities. Only recently has the synthetic community started to examine their potential as useful synthetic intermediates. Taking part in these efforts, the dual reactive nature of the metal vinylidene was illustrated in the context of rhodium vinylidene catalyzed enyne cycloisomerization via [2+2] cycloaddition and a nucleophile-triggered cycloisomerization of N-propargyl enamine derivatives.
590
$a
School code: 0181.
650
# 0
$a
Chemistry, Organic.
$3
193634
690
$a
0490
710
0 #
$a
Princeton University.
$3
212488
773
0 #
$g
68-01B.
$t
Dissertation Abstracts International
790
$a
0181
790
1 0
$a
Lee, Chulbom,
$e
advisor
791
$a
Ph.D.
792
$a
2007
856
4 0
$u
http://libsw.nuk.edu.tw:81/login?url=http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3250017
$z
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3250017
based on 0 review(s)
ALL
電子館藏
Items
1 records • Pages 1 •
1
Inventory Number
Location Name
Item Class
Material type
Call number
Usage Class
Loan Status
No. of reservations
Opac note
Attachments
000000007598
電子館藏
1圖書
電子書
TH
一般使用(Normal)
On shelf
0
1 records • Pages 1 •
1
Multimedia
Multimedia file
http://libsw.nuk.edu.tw:81/login?url=http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3250017
Reviews
Add a review
and share your thoughts with other readers
Export
pickup library
Processing
...
Change password
Login