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Morphological Control of Copper and ...

Mowbray, Ryan.

Morphological Control of Copper and Cuprous Oxide Nanoparticles via Synthesis and Oxidation/Reduction Reactions.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Morphological Control of Copper and Cuprous Oxide Nanoparticles via Synthesis and Oxidation/Reduction Reactions.
作者:	Mowbray, Ryan.
面頁冊數:	61 p.
附註:	Source: Masters Abstracts International, Volume: 51-06.
附註:	Adviser: Mark P. Stoykovich.
Contained By:	Masters Abstracts International51-06(E).
標題:	Engineering, Chemical.
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1539366
ISBN:	9781303144752

Morphological Control of Copper and Cuprous Oxide Nanoparticles via Synthesis and Oxidation/Reduction Reactions.
Mowbray, Ryan.

Morphological Control of Copper and Cuprous Oxide Nanoparticles via Synthesis and Oxidation/Reduction Reactions. - 61 p.

Source: Masters Abstracts International, Volume: 51-06.

Thesis (M.S.)--University of Colorado at Boulder, 2013.

Morphological structure at the nanoscale dictates material properties due to size and shape dependent effects which are not present in bulk materials. In this work, novel synthetic routes are presented for the synthesis of copper nanoparticles including cubes, octahedra and platelets which could find applications in catalysis and sensing applications. In addition, intermediate morphology of copper/cuprous oxide nanoparticles during reduction by hydrogen gas are characterized by UV-Vis spectroscopy and TEM imaging. The results of the UV-Vis characterization show that nanoparticle oxide reduction occurs by a different mechanism than reduction in the bulk due to short diffusion lengths and high metal diffusivity. The results of this work may be applied to the fields of catalysis, sensing, plasmonics, and spectroscopy where improved control of structure at the atomic level leads to improved functionality.

ISBN: 9781303144752Subjects--Topical Terms:

226989
Engineering, Chemical.

Morphological Control of Copper and Cuprous Oxide Nanoparticles via Synthesis and Oxidation/Reduction Reactions.
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245 1 0 $a Morphological Control of Copper and Cuprous Oxide Nanoparticles via Synthesis and Oxidation/Reduction Reactions.
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500 $a Adviser: Mark P. Stoykovich.
502 $a Thesis (M.S.)--University of Colorado at Boulder, 2013.
520 $a Morphological structure at the nanoscale dictates material properties due to size and shape dependent effects which are not present in bulk materials. In this work, novel synthetic routes are presented for the synthesis of copper nanoparticles including cubes, octahedra and platelets which could find applications in catalysis and sensing applications. In addition, intermediate morphology of copper/cuprous oxide nanoparticles during reduction by hydrogen gas are characterized by UV-Vis spectroscopy and TEM imaging. The results of the UV-Vis characterization show that nanoparticle oxide reduction occurs by a different mechanism than reduction in the bulk due to short diffusion lengths and high metal diffusivity. The results of this work may be applied to the fields of catalysis, sensing, plasmonics, and spectroscopy where improved control of structure at the atomic level leads to improved functionality.
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