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The development of rhodium-catalyzed...

Annis, Alexandra Helen.

The development of rhodium-catalyzed asymmetric hydroformylation of 1-alkenes to access chiral aldehydes.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	The development of rhodium-catalyzed asymmetric hydroformylation of 1-alkenes to access chiral aldehydes.
作者:	Annis, Alexandra Helen.
面頁冊數:	84 p.
附註:	Source: Masters Abstracts International, Volume: 55-01.
附註:	Adviser: James P. Morken.
Contained By:	Masters Abstracts International55-01(E).
標題:	Organic chemistry.
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1598129
ISBN:	9781339024134

The development of rhodium-catalyzed asymmetric hydroformylation of 1-alkenes to access chiral aldehydes.
Annis, Alexandra Helen.

The development of rhodium-catalyzed asymmetric hydroformylation of 1-alkenes to access chiral aldehydes. - 84 p.

Source: Masters Abstracts International, Volume: 55-01.

Thesis (M.S.)--Boston College, 2015.

Asymmetric hydroformylation (AHF) is a metal-catalyzed reaction in which CO and H2 are added across an olefin to form a new carbon-carbon bond. AHF has perfect atom-economy and is an ideal way to form a chiral aldehyde. However, the utility of branch selective hydroformylation is limited due to a lack of readily available ligands and restrictions on a wide variety of terminal olefins. Herein, Rh-catalyzed asymmetric hydroformylation of 1-alkenes is reported using commercially available Ph-BPE ligand to generate alpha-chiral aldehydes. A wide range of terminal olefins were explored and all showed high enantioselectivity (up to 98:2 er) and good regioselectivity (up to 15:1 branched to linear ratio).

ISBN: 9781339024134Subjects--Topical Terms:

708640
Organic chemistry.

The development of rhodium-catalyzed asymmetric hydroformylation of 1-alkenes to access chiral aldehydes.
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