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Optical properties and sensing appli...

Indiana University.

Optical properties and sensing applications of stellated and bimetallic nanoparticles.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Optical properties and sensing applications of stellated and bimetallic nanoparticles.
作者:	Smith, Alison F.
出版者:	Ann Arbor : ProQuest Dissertations & Theses, 2016
面頁冊數:	181 p.
附註:	Source: Dissertation Abstracts International, Volume: 78-04(E), Section: B.
附註:	Adviser: Sara E. Skrabalak.
Contained By:	Dissertation Abstracts International78-04B(E).
標題:	Materials science.
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10160712
ISBN:	9781369156188

Optical properties and sensing applications of stellated and bimetallic nanoparticles.
Smith, Alison F.

Optical properties and sensing applications of stellated and bimetallic nanoparticles. - Ann Arbor : ProQuest Dissertations & Theses, 2016 - 181 p.

Source: Dissertation Abstracts International, Volume: 78-04(E), Section: B.

Thesis (Ph.D.)--Indiana University, 2016.

This dissertation focuses on developing guidelines to aid in the design of new bimetallic platforms for sensing applications. Stellated metal nanostructures are a class of plasmonic colloids in which large electric field enhancements can occur at sharp features, making them excellent candidates for surface enhanced Raman spectroscopy (SERS) and surface enhanced infrared spectroscopy (SE-IRS) platforms. Shape-dependent rules for convex polyhedra such as cubes or octahedra exist, which describe far-field scattering and near-field enhancements. However, such rules are lacking for their concave (stellated) counterparts. This dissertation presents the optical response of stellated Au nanocrystals with Oh, D4h, D3h, C2v, and T d symmetry, which were modeled to systematically investigate the role of symmetry, branching, and particle orientation with respect to excitation source using finite difference time domain (FDTD) calculations. Expanding on stellated nanostructures, bimetallic compositions introduce an interplay between overall architecture and composition to provide tunable optical properties and the potential of new functionality. However, decoupling the complex compositional and structural contributions to the localized surface plasmon resonance (LSPR) remains a challenge, especially when the monometallic counterparts are not synthetically accessible for comparison and the theoretical tools for capturing gradient compositions are lacking. This dissertation explores a stellated Au-Pd nanocrystal model system with Oh symmetry to decouple structural and complex compositional effects on LSPR. (Abstract shortened by ProQuest.).

ISBN: 9781369156188Subjects--Topical Terms:

221779
Materials science.

Optical properties and sensing applications of stellated and bimetallic nanoparticles.
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