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Alkyne-based nanostructures on silve...

Hellwig, Raphael.

Alkyne-based nanostructures on silver substrates

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Alkyne-based nanostructures on silver substratesby Raphael Hellwig.
作者:	Hellwig, Raphael.
出版者:	Cham :Springer International Publishing :2018.
面頁冊數:	xv, 119 p. :ill. (some col.), digital ;24 cm.
Contained By:	Springer eBooks
標題:	Nanostructured materials.
電子資源:	https://doi.org/10.1007/978-3-030-00997-7
ISBN:	9783030009977$q(electronic bk.)

Alkyne-based nanostructures on silver substrates
Hellwig, Raphael.

Alkyne-based nanostructures on silver substrates[electronic resource] /by Raphael Hellwig. - Cham :Springer International Publishing :2018. - xv, 119 p. :ill. (some col.), digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

Introduction -- Experimental Methods -- Silver-bis-acetylide Wires -- Fabrication of Graphdiyne Nanowires -- Metal Alkynyl 22/7 Complexes -- Ho-Catalyzed Cyclotrimerization -- Conclusion and Outlook.

Acetylenic precursors are important reactants for creating carbon-based architectures via linkage reactions. While their capability of forming intermolecular bonds is well investigated in solution, very few systematic studies have been carried out to create alkyne-based nanostructures on metal substrates under ultra-high vacuum conditions. Synthesizing extended and regular carbon scaffolds requires a detailed knowledge of alkyne chemistry in order to control reaction pathways and limit unwanted side reactions. Using the bottom-up approach on metal surfaces, the author establishes protocols to fabricate regular architectures built up by the on-surface formation of selective organometallic and C-C bonds with thoughtfully designed alkyne-functionalized monomers. The structural and functional properties of the resulting organometallic and covalent nanostructures are characterized by means of scanning tunneling microscopy. The results open up new perspectives in the fields of heterogeneous catalysis and the on-surface synthesis of functional interfaces under mild reaction conditions.

ISBN: 9783030009977$q(electronic bk.)

Standard No.: 10.1007/978-3-030-00997-7doiSubjects--Topical Terms:

216041
Nanostructured materials.

LC Class. No.: TA418.9.N35 / H455 2018

Dewey Class. No.: 620.115

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