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Chemistry of thioamides

Murai, Toshiaki.

Chemistry of thioamides

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Chemistry of thioamidesedited by Toshiaki Murai.
其他作者:	Murai, Toshiaki.
出版者:	Singapore :Springer Singapore :2019.
面頁冊數:	vii, 238 p. :ill., digital ;24 cm.
Contained By:	Springer eBooks
標題:	Sulfur.
電子資源:	https://doi.org/10.1007/978-981-13-7828-7
ISBN:	9789811378287$q(electronic bk.)

Chemistry of thioamides
Chemistry of thioamides[electronic resource] /edited by Toshiaki Murai. - Singapore :Springer Singapore :2019. - vii, 238 p. :ill., digital ;24 cm.

1. Thioamides : Overview -- 2. Theoretical Aspects of Thioamides -- 3. Synthesis of Thioamides -- 4. Reaction of Thioamides -- 5. Asymmetric Synthesis Using Thioamides -- 6. Synthesis of Heterocycles from Thioamides -- 7.Thioamides-based Transition Metal-complexes -- 8. Thioamide-containing Peptides and Proteins.

This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon-sulfur and carbon-carbon bonds, to asymmetric reactions, to formation of heterocycles are described. Among the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features. Thioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologically relevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book.

ISBN: 9789811378287$q(electronic bk.)

Standard No.: 10.1007/978-981-13-7828-7doiSubjects--Topical Terms:

667893
Sulfur.

LC Class. No.: QD181.S1 / C446 2019

Dewey Class. No.: 546.723

Chemistry of thioamides
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505 0 $a 1. Thioamides : Overview -- 2. Theoretical Aspects of Thioamides -- 3. Synthesis of Thioamides -- 4. Reaction of Thioamides -- 5. Asymmetric Synthesis Using Thioamides -- 6. Synthesis of Heterocycles from Thioamides -- 7.Thioamides-based Transition Metal-complexes -- 8. Thioamide-containing Peptides and Proteins.
520 $a This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon-sulfur and carbon-carbon bonds, to asymmetric reactions, to formation of heterocycles are described. Among the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features. Thioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologically relevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book.
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