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Frustrated Magnetism in Hexagonal Perovskites as Quantum Spin Liquid Candidates.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Frustrated Magnetism in Hexagonal Perovskites as Quantum Spin Liquid Candidates.
作者:	Nguyen, Loi Thanh.
出版者:	Ann Arbor : ProQuest Dissertations & Theses, 2021
面頁冊數:	349 p.
附註:	Source: Dissertations Abstracts International, Volume: 83-04, Section: B.
附註:	Advisor: Cava, Robert J.
Contained By:	Dissertations Abstracts International83-04B.
標題:	Chemistry.
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28646579
ISBN:	9798471107489

Frustrated Magnetism in Hexagonal Perovskites as Quantum Spin Liquid Candidates.
Nguyen, Loi Thanh.

Frustrated Magnetism in Hexagonal Perovskites as Quantum Spin Liquid Candidates. - Ann Arbor : ProQuest Dissertations & Theses, 2021 - 349 p.

Source: Dissertations Abstracts International, Volume: 83-04, Section: B.

Thesis (Ph.D.)--Princeton University, 2021.

This item must not be sold to any third party vendors.

Hexagonal oxide perovskites, in contrast to the more familiar perovskites, allow for face-sharing of metal-oxygen octahedra or trigonal prisms within their structural frameworks. This results in dimers, trimers, tetramers, or longer fragments of chains of face-sharing octahedra in the crystal structures, and consequently in much shorter metal-metal distances and lower metal-oxygen-metal bond angles than are seen in the more familiar perovskites. The presence of the face-sharing octahedra can have a dramatic impact on magnetic properties of these compounds, and dimer-based materials, for example, have been the subjects of many quantum-materials-directed studies in materials physics. Hexagonal oxide perovskites are also of contemporary interest due to their potential for geometrical frustration of the ordering of magnetic moments or orbital occupancies at low temperatures, which is especially relevant to their significance as quantum materials. As such, several hexagonal oxide perovskites have been identified as potential candidates for hosting the quantum spin liquid state at low temperatures. Therefore, hexagonal oxide perovskites are fertile ground for finding new quantum materials. This thesis briefly describes the solid state chemistry of many of these materials.

ISBN: 9798471107489Subjects--Topical Terms:

188628
Chemistry.
Subjects--Index Terms:

Face-sharing octahedra

Frustrated Magnetism in Hexagonal Perovskites as Quantum Spin Liquid Candidates.
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