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Metallocenes in regio- and stereoselective synthesis

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Metallocenes in regio- and stereoselective synthesisedited by Marko Hapke, Martin Kotora.
其他作者:	Hapke, Marko.
出版者:	Cham :Springer International Publishing :2024.
面頁冊數:	vii, 204 p. :ill., digital ;24 cm.
Contained By:	Springer Nature eBook
標題:	MetallocenesSynthesis.
電子資源:	https://doi.org/10.1007/978-3-031-57381-1
ISBN:	9783031573811$q(electronic bk.)

Metallocenes in regio- and stereoselective synthesis
Metallocenes in regio- and stereoselective synthesis[electronic resource] /edited by Marko Hapke, Martin Kotora. - Cham :Springer International Publishing :2024. - vii, 204 p. :ill., digital ;24 cm. - Topics in organometallic chemistry,741616-8534 ;. - Topics in organometallic chemistry ;38.

Synthesis and Application of Highly Substituted Cyclopentadienes -- Synthesis of 1,2-Disubstituted Cyclopentadienes and Their Application -- Synthesis and application of novel chiral Cp ligands in transition metal catalysis -- Selective synthesis of and with chiral ferrocenes -- Knölker-type catalysts for (asymmetric) hydrogenation reactions -- Selective transformations mediated by group 4 metal cyclopentadienyl complexes -- Naturally Occurring Cyclopentadienes and Cyclopentadienyl Anions -- Naturally Occurring Diazofluorenes.

This book presents the latest synthetic protocols for the assembly of functionalized Cp ligands and their transition metal complexes. Cyclopentadienyl (Cp) complexes of transition metals belong to the most important classes of transition metal complexes with s-bound ligands in the coordination sphere since their discovery in the middle of the last century. Even though known for a long time, this class of complexes constantly evolves to deliver novel modified Cp ligands and to blossom into new fields of application. As well as the synthesis of ligands and complexes this book concentrates on novel and prospering fields of application in organic synthesis. In this respect the Cp complexes have been applied to induce and catalyze various chemical transformations such as new C-C bond formation involving unsaturated substrates (e.g. cyclotrimerizations, cycloadditions, carbometallations, etc.), the C-H bond and C-C activations followed by subsequent reactions (e.g. arylation, alkenylations, annulations, etc.), as well as many other processes which are discussed. This volume also covers the recent application of chiral Cp complexes in enantioselective synthesis and as essential parts of many ligand systems.

ISBN: 9783031573811$q(electronic bk.)

Standard No.: 10.1007/978-3-031-57381-1doiSubjects--Topical Terms:

970274
Metallocenes
--Synthesis.

LC Class. No.: QD411.7.S94 / M48 2024

Dewey Class. No.: 547.2

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520 $a This book presents the latest synthetic protocols for the assembly of functionalized Cp ligands and their transition metal complexes. Cyclopentadienyl (Cp) complexes of transition metals belong to the most important classes of transition metal complexes with s-bound ligands in the coordination sphere since their discovery in the middle of the last century. Even though known for a long time, this class of complexes constantly evolves to deliver novel modified Cp ligands and to blossom into new fields of application. As well as the synthesis of ligands and complexes this book concentrates on novel and prospering fields of application in organic synthesis. In this respect the Cp complexes have been applied to induce and catalyze various chemical transformations such as new C-C bond formation involving unsaturated substrates (e.g. cyclotrimerizations, cycloadditions, carbometallations, etc.), the C-H bond and C-C activations followed by subsequent reactions (e.g. arylation, alkenylations, annulations, etc.), as well as many other processes which are discussed. This volume also covers the recent application of chiral Cp complexes in enantioselective synthesis and as essential parts of many ligand systems.
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