國立高雄大學圖資館 |

Language: English

Back

探討最佳化結構與雙層陽極緩衝層對有機太陽能電池效率之研究 = Inves...

國立高雄大學應用物理學系碩士班

探討最佳化結構與雙層陽極緩衝層對有機太陽能電池效率之研究 = Investigation of the optimal structure and the double anode buffer layers for the efficiency of organic solar cells

Record Type:	Language materials, printed : monographic
Paralel Title:	Investigation of the optimal structure and the double anode buffer layers for the efficiency of organic solar cells
Author:	柯中喬,
Secondary Intellectual Responsibility:	國立高雄大學
Place of Publication:	[高雄市]
Published:	撰者;
Year of Publication:	民100
Description:	76葉圖，表格 : 30公分;
Subject:	有機太陽能電池
Subject:	power conversion efficiency
Online resource:	http://handle.ncl.edu.tw/11296/ndltd/07960178844414521536
Notes:	參考書目：葉35-37
Summary:	在本研究中，最佳化結構是從一般常用的結構ITO/CuPc (20nm)/C60 (30nm)/BCP(10nm)/Al調整元件主動層的厚度與結構，使得短路電流3.09 mA/cm2上升到5.11 mA/cm2，開路電壓從0.4V上升到0.47V，轉換效率從0.66%上升到1.28%在AM1.5G的太陽能光譜下。這些增加是歸因於在光的吸收效率和載子的分離效率以及載子的收集效率之間達到一個最佳的平衡，使得短路電流能有所提升而不會影響到元件的填充因子的值。最後得到有機太陽能電池最佳化結構為：ITO/CuPc (10nm)/CuPc:C60 (20nm)/C60 (20nm)/BCP(10nm)/Al。。為了更進一步地增加元件的效率，我們在最佳化結構的基礎下，在ITO及CuPc之間插入PEDOT: PSS(有摻雜sorbitol)與pentacene雙層陽極緩衝層來幫助元件電洞的收集效率，元件的結構為ITO/PEDOT: PSS (doped with 4wt% sorbitol)/ pentacene (2nm)/CuPc (10nm)/ CuPc: C60 mixed (20nm)/C60 (20nm)/BCP (10nm)/Al。因此藉由雙層陽極緩衝層插入元件使得轉換效率大幅度的增加。短路電流提升了三倍之多，使得元件的轉換效率達到3.9%。 In this study, small molecule organic solar cell with an optimized structure of ITO/CuPc 10nm/CuPc:C60 (20nm)/C60 (20nm)/BCP (10nm)/Al) was fabricated. With optimizing the above structure from the conventional structure of ITO/CuPc (20nm)/C60 (30nm)/BCP (10nm)/Al, the short-circuit current density (Jsc) increased from 3.09 mA/cm2 to 5.11mA/cm2, the open-circuit voltage (Voc) increased from 0.40 to 0.47V, and the power conversion efficiency (ηp) increased from 0.66 to 1.28% under 100mW/cm2 AM1.5G illumination. These improvements were attributed to reach the optimal balance among the light absorption efficiency, the exciton dissociation efficiency and the carrier collection efficiency of the device, resulting in enhancement of Jsc without affecting the value of fill factor (FF) and the reduction of the dark current.Based on the optimal structure, we incorporated PEDOT: PSS layer doped with 4wt% sorbitol and pentacene layer as interlayers between the ITO anode and CuPc layer to help the hole transport. The small molecule organic solar cell with structure of ITO/PEDOT: PSS (doped with 4wt% sorbitol)/ pentacene (2nm)/CuPc (10nm)/ CuPc: C60 mixed (20nm)/C60 (20nm)/BCP (10nm)/Al. And then the short-circuit current (Jsc) of solar cell was enhanced by inserting both the PEDOT: PSS (4wt% sorbitol) and the pentacene, resulting in a 300% enhancement in power conversion efficiency (PCE). The maximum PCE of 3.9% was obtained under 1sun standard AM1.5G solar illumination of 100mW/cm2.

探討最佳化結構與雙層陽極緩衝層對有機太陽能電池效率之研究 = Investigation of the optimal structure and the double anode buffer layers for the efficiency of organic solar cells
柯, 中喬

探討最佳化結構與雙層陽極緩衝層對有機太陽能電池效率之研究 = Investigation of the optimal structure and the double anode buffer layers for the efficiency of organic solar cells / 柯中喬撰 - [高雄市] : 撰者, 民100. - 76葉 ; 圖，表格 ; 30公分.
參考書目：葉35-37.
有機太陽能電池power conversion efficiency

探討最佳化結構與雙層陽極緩衝層對有機太陽能電池效率之研究 = Investigation of the optimal structure and the double anode buffer layers for the efficiency of organic solar cells
LDR:03839nam0a2200277 450 001 300482
005 20170214095432.0
009 300482
010 0 $b 精裝
010 0 $b 平裝
100 $a 20170214d2011 k y0chiy50 e
101 1 $a eng $d chi $d eng
102 $a tw
105 $a ak am 000yy
200 1 $a 探討最佳化結構與雙層陽極緩衝層對有機太陽能電池效率之研究 $d Investigation of the optimal structure and the double anode buffer layers for the efficiency of organic solar cells $z eng $f 柯中喬撰
210 $a [高雄市] $c 撰者 $d 民100
215 0 $a 76葉 $c 圖，表格 $d 30公分
300 $a 參考書目：葉35-37
314 $a 指導教授：黃建榮博士
328 $a 碩士論文--國立高雄大學應用物理學系碩士班
330 $a 在本研究中，最佳化結構是從一般常用的結構ITO/CuPc (20nm)/C60 (30nm)/BCP(10nm)/Al調整元件主動層的厚度與結構，使得短路電流3.09 mA/cm2上升到5.11 mA/cm2，開路電壓從0.4V上升到0.47V，轉換效率從0.66%上升到1.28%在AM1.5G的太陽能光譜下。這些增加是歸因於在光的吸收效率和載子的分離效率以及載子的收集效率之間達到一個最佳的平衡，使得短路電流能有所提升而不會影響到元件的填充因子的值。最後得到有機太陽能電池最佳化結構為：ITO/CuPc (10nm)/CuPc:C60 (20nm)/C60 (20nm)/BCP(10nm)/Al。。為了更進一步地增加元件的效率，我們在最佳化結構的基礎下，在ITO及CuPc之間插入PEDOT: PSS(有摻雜sorbitol)與pentacene雙層陽極緩衝層來幫助元件電洞的收集效率，元件的結構為ITO/PEDOT: PSS (doped with 4wt% sorbitol)/ pentacene (2nm)/CuPc (10nm)/ CuPc: C60 mixed (20nm)/C60 (20nm)/BCP (10nm)/Al。因此藉由雙層陽極緩衝層插入元件使得轉換效率大幅度的增加。短路電流提升了三倍之多，使得元件的轉換效率達到3.9%。 In this study, small molecule organic solar cell with an optimized structure of ITO/CuPc 10nm/CuPc:C60 (20nm)/C60 (20nm)/BCP (10nm)/Al) was fabricated. With optimizing the above structure from the conventional structure of ITO/CuPc (20nm)/C60 (30nm)/BCP (10nm)/Al, the short-circuit current density (Jsc) increased from 3.09 mA/cm2 to 5.11mA/cm2, the open-circuit voltage (Voc) increased from 0.40 to 0.47V, and the power conversion efficiency (ηp) increased from 0.66 to 1.28% under 100mW/cm2 AM1.5G illumination. These improvements were attributed to reach the optimal balance among the light absorption efficiency, the exciton dissociation efficiency and the carrier collection efficiency of the device, resulting in enhancement of Jsc without affecting the value of fill factor (FF) and the reduction of the dark current.Based on the optimal structure, we incorporated PEDOT: PSS layer doped with 4wt% sorbitol and pentacene layer as interlayers between the ITO anode and CuPc layer to help the hole transport. The small molecule organic solar cell with structure of ITO/PEDOT: PSS (doped with 4wt% sorbitol)/ pentacene (2nm)/CuPc (10nm)/ CuPc: C60 mixed (20nm)/C60 (20nm)/BCP (10nm)/Al. And then the short-circuit current (Jsc) of solar cell was enhanced by inserting both the PEDOT: PSS (4wt% sorbitol) and the pentacene, resulting in a 300% enhancement in power conversion efficiency (PCE). The maximum PCE of 3.9% was obtained under 1sun standard AM1.5G solar illumination of 100mW/cm2.
510 1 $a Investigation of the optimal structure and the double anode buffer layers for the efficiency of organic solar cells $z eng
610 0 $a 有機太陽能電池 $a 轉換效率 $a 五環素
610 1 $a power conversion efficiency $a organic solar cell $a pentacene
681 $a 008M/0019 $b 423203 4152 $v 2007年版
700 1 $a 柯 $b 中喬 $4 撰 $3 518873
712 0 2 $a 國立高雄大學 $b 應用物理學系碩士班 $3 353956
801 0 $a tw $b NUK $c 20111028 $g CCR
856 7 $z 電子資源 $2 http $u http://handle.ncl.edu.tw/11296/ndltd/07960178844414521536