語系:
繁體中文
English
說明(常見問題)
圖資館首頁
登入
回首頁
切換:
標籤
|
MARC模式
|
ISBD
Palladium and nickel catalyzed trans...
~
SpringerLink (Online service)
Palladium and nickel catalyzed transformations forming functionalized heterocycles
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Palladium and nickel catalyzed transformations forming functionalized heterocyclesby Hyung Yoon.
作者:
Yoon, Hyung.
出版者:
Cham :Springer International Publishing :2020.
面頁冊數:
xxix, 212 p. :ill., digital ;24 cm.
Contained By:
Springer Nature eBook
標題:
Heterocyclic compounds.
電子資源:
https://doi.org/10.1007/978-3-030-54077-7
ISBN:
9783030540777$q(electronic bk.)
Palladium and nickel catalyzed transformations forming functionalized heterocycles
Yoon, Hyung.
Palladium and nickel catalyzed transformations forming functionalized heterocycles
[electronic resource] /by Hyung Yoon. - Cham :Springer International Publishing :2020. - xxix, 212 p. :ill., digital ;24 cm. - Springer theses,2190-5053. - Springer theses..
Chapter 1. Carbohalogenation Catalyzed by Palladium and Nickel -- Chapter 2. Diastereoselective Pd-Catalyzed Aryl Cyanation and Aryl Borylation -- Chapter 3. Pd-Catalyzed Spirocyclization via C-H Activation and Benzyne/Alkyne Insertion.
This book presents Pd- and Ni-catalyzed transformations generating functionalized heterocycles. Transition metal catalysis is at the forefront of synthetic organic chemistry since it offers new and powerful methods to forge carbon-carbon bonds in high atom- and step-economy. In Chapter 1, the author describes a Pd- and Ni-catalyzed cycloisomerization of aryl iodides to alkyl iodides, known as carboiodination. In the context of the Pd-catalyzed variant, the chapter explores the production of enantioenriched carboxamides through diastereoselective Pd-catalyzed carboiodination. It then discusses Ni-catalyzed reactions to generate oxindoles and an enantioselective variant employing a dual ligand system. Chapter 2 introduces readers to a Pd-catalyzed diastereoselective anion-capture cascade. It also examines diastereoselective Pd-catalyzed aryl cyanation to synthesize alkyl nitriles, a method that generates high yields of borylated chromans as a single diastereomer, and highlights its synthetic utility. Lastly, Chapter 3 presents a Pd-catalyzed domino process harnessing carbopalladation, C-H activation and π-system insertion (benzynes and alkynes) to generate spirocycles. It also describes the mechanistic studies performed on these reactions.
ISBN: 9783030540777$q(electronic bk.)
Standard No.: 10.1007/978-3-030-54077-7doiSubjects--Topical Terms:
235305
Heterocyclic compounds.
LC Class. No.: QD505 / .Y666 2020
Dewey Class. No.: 541.395
Palladium and nickel catalyzed transformations forming functionalized heterocycles
LDR
:02550nmm a2200337 a 4500
001
585062
003
DE-He213
005
20201221133241.0
006
m d
007
cr nn 008maaau
008
210311s2020 sz s 0 eng d
020
$a
9783030540777$q(electronic bk.)
020
$a
9783030540760$q(paper)
024
7
$a
10.1007/978-3-030-54077-7
$2
doi
035
$a
978-3-030-54077-7
040
$a
GP
$c
GP
041
0
$a
eng
050
4
$a
QD505
$b
.Y666 2020
072
7
$a
PNRD
$2
bicssc
072
7
$a
SCI013060
$2
bisacsh
072
7
$a
PNRD
$2
thema
082
0 4
$a
541.395
$2
23
090
$a
QD505
$b
.Y59 2020
100
1
$a
Yoon, Hyung.
$3
875922
245
1 0
$a
Palladium and nickel catalyzed transformations forming functionalized heterocycles
$h
[electronic resource] /
$c
by Hyung Yoon.
260
$a
Cham :
$b
Springer International Publishing :
$b
Imprint: Springer,
$c
2020.
300
$a
xxix, 212 p. :
$b
ill., digital ;
$c
24 cm.
490
1
$a
Springer theses,
$x
2190-5053
505
0
$a
Chapter 1. Carbohalogenation Catalyzed by Palladium and Nickel -- Chapter 2. Diastereoselective Pd-Catalyzed Aryl Cyanation and Aryl Borylation -- Chapter 3. Pd-Catalyzed Spirocyclization via C-H Activation and Benzyne/Alkyne Insertion.
520
$a
This book presents Pd- and Ni-catalyzed transformations generating functionalized heterocycles. Transition metal catalysis is at the forefront of synthetic organic chemistry since it offers new and powerful methods to forge carbon-carbon bonds in high atom- and step-economy. In Chapter 1, the author describes a Pd- and Ni-catalyzed cycloisomerization of aryl iodides to alkyl iodides, known as carboiodination. In the context of the Pd-catalyzed variant, the chapter explores the production of enantioenriched carboxamides through diastereoselective Pd-catalyzed carboiodination. It then discusses Ni-catalyzed reactions to generate oxindoles and an enantioselective variant employing a dual ligand system. Chapter 2 introduces readers to a Pd-catalyzed diastereoselective anion-capture cascade. It also examines diastereoselective Pd-catalyzed aryl cyanation to synthesize alkyl nitriles, a method that generates high yields of borylated chromans as a single diastereomer, and highlights its synthetic utility. Lastly, Chapter 3 presents a Pd-catalyzed domino process harnessing carbopalladation, C-H activation and π-system insertion (benzynes and alkynes) to generate spirocycles. It also describes the mechanistic studies performed on these reactions.
650
0
$a
Heterocyclic compounds.
$3
235305
650
0
$a
Catalysis.
$3
188259
650
0
$a
Chemistry, Inorganic.
$3
197298
650
0
$a
Chemistry, Organic.
$3
193634
650
0
$a
Organometallic chemistry.
$3
194019
650
0
$a
Chemistry, Physical and theoretical.
$3
188610
650
2 4
$a
Inorganic Chemistry.
$3
273692
650
2 4
$a
Organic Chemistry.
$3
274120
650
2 4
$a
Organometallic Chemistry.
$3
275305
650
2 4
$a
Physical Chemistry.
$3
273698
710
2
$a
SpringerLink (Online service)
$3
273601
773
0
$t
Springer Nature eBook
830
0
$a
Springer theses.
$3
557607
856
4 0
$u
https://doi.org/10.1007/978-3-030-54077-7
950
$a
Chemistry and Materials Science (SpringerNature-11644)
筆 0 讀者評論
全部
電子館藏
館藏
1 筆 • 頁數 1 •
1
條碼號
館藏地
館藏流通類別
資料類型
索書號
使用類型
借閱狀態
預約狀態
備註欄
附件
000000188998
電子館藏
1圖書
電子書
EB QD505 .Y59 2020 2020
一般使用(Normal)
在架
0
1 筆 • 頁數 1 •
1
多媒體
多媒體檔案
https://doi.org/10.1007/978-3-030-54077-7
評論
新增評論
分享你的心得
Export
取書館別
處理中
...
變更密碼
登入