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Photochemical and electrochemical activation strategies of C(sp3)-based building blocks for organic synthesis

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Photochemical and electrochemical activation strategies of C(sp3)-based building blocks for organic synthesisby Su Yong Go.
作者:	Go, Su Yong.
出版者:	Singapore :Springer Nature Singapore :2024.
面頁冊數:	xxvii, 169 p. :ill. (some col.), digital ;24 cm.
Contained By:	Springer Nature eBook
標題:	Organic compoundsSynthesis.
電子資源:	https://doi.org/10.1007/978-981-99-8994-2
ISBN:	9789819989942$q(electronic bk.)

Photochemical and electrochemical activation strategies of C(sp3)-based building blocks for organic synthesis
Go, Su Yong.

Photochemical and electrochemical activation strategies of C(sp3)-based building blocks for organic synthesis[electronic resource] /by Su Yong Go. - Singapore :Springer Nature Singapore :2024. - xxvii, 169 p. :ill. (some col.), digital ;24 cm. - Springer theses,2190-5061. - Springer theses..

Part I. C(sp2)-C(sp3) Bond Formation Reactions Enabled by Photoredox/Nickel Dual Catalysis -- Chapter 1. The Key Concepts and Strategy in Photoredox/Nickel Dual Catalysis and Application to C-C Bond Formation Reactions -- Chapter 2. Highl Regioselective and E/Z Selective Hydroalkylation of Alkyne via Photoredox Mediated Ni/Ir Dual Catalysis -- Part II. Development of C(sp3)-Heteroatom Bond-Forming Reactions via Electrochemical Activation of C(sp3)-B Bonds and Follow-up Projects -- Chapter 3. Recent Achievements of C(sp3)-Heteroatom Bond Formation in Electroorganic Synthesis and History of C(sp3)-B Bond Activation -- Chapter 4. Introduction of Heteroatoms to Alkyl Carbocations Generated from Alkylboron Reagents via Electrochemical Activation -- Chapter 5. Functionalization of Alkylboron Compounds Under Other Reaction Conditions.

This book addresses novel C(sp3)-C(sp2) and C(sp3)-heteroatom bond-forming reactions. Two strategies are given in the book using photoredox or electrochemical methods. The first strategy describes that the hydroalkylation of alkynes via photoredox-mediated Ni/Ir dual catalysis produces trisubstituted alkenes as versatile synthetic building blocks for the synthesis of pharmaceutical agents and natural products. High regioselectivity and E/Z-selectivity were achieved by introducing silyl groups that can provide steric and electronic effects to these selectivities with extensive opportunities for post-functionalization. The second strategy enables the development of C(sp3)-heteroatom bond-forming reactions through the electrochemical activation of C(sp3)-B bonds. The bonding of heteroatoms to carbon atoms has been an enduring subject of investigation for organic chemists. The function of most molecules is mainly determined by heteroatoms attached to the carbon atom, although the backbone structure of organic compounds comprises carbon fragments.

ISBN: 9789819989942$q(electronic bk.)

Standard No.: 10.1007/978-981-99-8994-2doiSubjects--Topical Terms:

193643
Organic compounds
--Synthesis.

LC Class. No.: QD262

Dewey Class. No.: 547.2

Photochemical and electrochemical activation strategies of C(sp3)-based building blocks for organic synthesis
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520 $a This book addresses novel C(sp3)-C(sp2) and C(sp3)-heteroatom bond-forming reactions. Two strategies are given in the book using photoredox or electrochemical methods. The first strategy describes that the hydroalkylation of alkynes via photoredox-mediated Ni/Ir dual catalysis produces trisubstituted alkenes as versatile synthetic building blocks for the synthesis of pharmaceutical agents and natural products. High regioselectivity and E/Z-selectivity were achieved by introducing silyl groups that can provide steric and electronic effects to these selectivities with extensive opportunities for post-functionalization. The second strategy enables the development of C(sp3)-heteroatom bond-forming reactions through the electrochemical activation of C(sp3)-B bonds. The bonding of heteroatoms to carbon atoms has been an enduring subject of investigation for organic chemists. The function of most molecules is mainly determined by heteroatoms attached to the carbon atom, although the backbone structure of organic compounds comprises carbon fragments.
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