國立高雄大學圖資館 |

Language: English

Back

Controlling the work function of indium tin oxide with organometallic surface complexes.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Controlling the work function of indium tin oxide with organometallic surface complexes.
Author:	Bruner, Eric Lawrence.
Description:	128 p.
Notes:	Source: Dissertation Abstracts International, Volume: 63-10, Section: B, page: 4645.
Contained By:	Dissertation Abstracts International63-10B.
Subject:	Chemistry, General.
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3068785
ISBN:	0493884319

Controlling the work function of indium tin oxide with organometallic surface complexes.
Bruner, Eric Lawrence.

Controlling the work function of indium tin oxide with organometallic surface complexes. [electronic resource] - 128 p.

Source: Dissertation Abstracts International, Volume: 63-10, Section: B, page: 4645.

Thesis (Ph.D.)--Princeton University, 2003.

The reactions of tetra(tert-butoxy)tin and tetrakis(diethylamino)tin with indium in oxide (ITO) give surface-bound tin alkoxide and tin amide complexes respectively. Organic acids with appropriate acidities initiate ligand metathesis with these surface complexes. Surface bound (arylacetylide)tin and (phenoxide)tin species were synthesized in ultra-high vacuum and characterized by X-ray photoelectron spectroscopy, mass spectrometry, and reflective absorption infrared spectroscopy. A series of substituted phenols, with a range of dipole moments and acidities, was reacted with surface-bound tin alkoxide to probe the validity of a dipole-moment model. The use of o- and p-substituted phenoxytin surface complexes demonstrated that dipolar properties of the surface bound species, and not local electronegativity effects, control the work function of ITO.

ISBN: 0493884319Subjects--Topical Terms:

226910
Chemistry, General.

Controlling the work function of indium tin oxide with organometallic surface complexes.
LDR:01741nmm _2200229 _450 001 161834
005 20051017073342.5
008 230606s2003 eng d
020 $a 0493884319
035 $a 00148335
035 $a 161834
040 $a UnM $c UnM
100 0 $a Bruner, Eric Lawrence. $3 226909
245 1 0 $a Controlling the work function of indium tin oxide with organometallic surface complexes. $h [electronic resource]
300 $a 128 p.
500 $a Source: Dissertation Abstracts International, Volume: 63-10, Section: B, page: 4645.
502 $a Thesis (Ph.D.)--Princeton University, 2003.
520 # $a The reactions of tetra(tert-butoxy)tin and tetrakis(diethylamino)tin with indium in oxide (ITO) give surface-bound tin alkoxide and tin amide complexes respectively. Organic acids with appropriate acidities initiate ligand metathesis with these surface complexes. Surface bound (arylacetylide)tin and (phenoxide)tin species were synthesized in ultra-high vacuum and characterized by X-ray photoelectron spectroscopy, mass spectrometry, and reflective absorption infrared spectroscopy. A series of substituted phenols, with a range of dipole moments and acidities, was reacted with surface-bound tin alkoxide to probe the validity of a dipole-moment model. The use of o- and p-substituted phenoxytin surface complexes demonstrated that dipolar properties of the surface bound species, and not local electronegativity effects, control the work function of ITO.
590 $a School code: 0181.
650 # 0 $a Chemistry, General. $3 226910
710 0 # $a Princeton University. $3 212488
773 0 # $g 63-10B. $t Dissertation Abstracts International
790 $a 0181
791 $a Ph.D.
792 $a 2003
856 4 0 $u http://libsw.nuk.edu.tw/login?url=http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3068785 $z http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3068785