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Spectroscopic investigations of fund...

Diken, Eric G.

Spectroscopic investigations of fundamental chemical reactions and the cooperativity of hydrogen bonds in solvated clusters.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Spectroscopic investigations of fundamental chemical reactions and the cooperativity of hydrogen bonds in solvated clusters.
Author:	Diken, Eric G.
Description:	181 p.
Notes:	Director: Mark A. Johnson.
Notes:	Source: Dissertation Abstracts International, Volume: 66-11, Section: B, page: 5995.
Contained By:	Dissertation Abstracts International66-11B.
Subject:	Chemistry, Physical.
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3194640
ISBN:	9780542393068

Spectroscopic investigations of fundamental chemical reactions and the cooperativity of hydrogen bonds in solvated clusters.
Diken, Eric G.

Spectroscopic investigations of fundamental chemical reactions and the cooperativity of hydrogen bonds in solvated clusters. - 181 p.

Director: Mark A. Johnson.

Thesis (Ph.D.)--Yale University, 2005.

This thesis focuses on understanding the cooperativity and high-directionality of hydrogen bonds in several model systems, as well as the physical processes that drive elementary ion-molecule reactions such as proton transfer or H-atom abstraction. These fundamental interactions are examined at the molecular level where the solvent molecules are, in most cases, clustered together with a solute ion in the gaseous phase and directly probed using various frequency-domain laser spectroscopic techniques. In particular, vibrational predissociation spectroscopy and negative-ion photoelectron spectroscopy were utilized, in conjunction with modern electronic structure calculations, to investigate the details of the hydrogen bonds formed in the initial stages of solvation or during the course of bimolecular chemical reactions. The molecular systems examined in this thesis span a wide variety of interests and include anion-water binary complexes, hydrated biomolecules, and neutral water clusters, in addition to the larger ammonium-water clathrate complexes.

ISBN: 9780542393068Subjects--Topical Terms:

226924
Chemistry, Physical.

Spectroscopic investigations of fundamental chemical reactions and the cooperativity of hydrogen bonds in solvated clusters.
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245 1 0 $a Spectroscopic investigations of fundamental chemical reactions and the cooperativity of hydrogen bonds in solvated clusters.
300 $a 181 p.
500 $a Director: Mark A. Johnson.
500 $a Source: Dissertation Abstracts International, Volume: 66-11, Section: B, page: 5995.
502 $a Thesis (Ph.D.)--Yale University, 2005.
520 # $a This thesis focuses on understanding the cooperativity and high-directionality of hydrogen bonds in several model systems, as well as the physical processes that drive elementary ion-molecule reactions such as proton transfer or H-atom abstraction. These fundamental interactions are examined at the molecular level where the solvent molecules are, in most cases, clustered together with a solute ion in the gaseous phase and directly probed using various frequency-domain laser spectroscopic techniques. In particular, vibrational predissociation spectroscopy and negative-ion photoelectron spectroscopy were utilized, in conjunction with modern electronic structure calculations, to investigate the details of the hydrogen bonds formed in the initial stages of solvation or during the course of bimolecular chemical reactions. The molecular systems examined in this thesis span a wide variety of interests and include anion-water binary complexes, hydrated biomolecules, and neutral water clusters, in addition to the larger ammonium-water clathrate complexes.
590 $a School code: 0265.
650 # 0 $a Chemistry, Physical. $3 226924
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710 0 # $a Yale University. $3 212430
773 0 # $g 66-11B. $t Dissertation Abstracts International
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790 1 0 $a Johnson, Mark A., $e advisor
791 $a Ph.D.
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