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Chemical kineticsfrom molecular stru...
~
Arnaut, Lu�is G., (1960-)
Chemical kineticsfrom molecular structure to chemical reactivity /
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Chemical kineticsLuis Arnaut, Sebastiao Formosinho, Hugh Burrows.
其他題名:
from molecular structure to chemical reactivity /
作者:
Arnaut, Lu�is G.,
其他作者:
Burrows, Hugh.
出版者:
Amsterdam ;Elsevier,2007.
面頁冊數:
xii, 549 p. :ill. ;25 cm.
標題:
Chemical kinetics.
電子資源:
An electronic book accessible through the World Wide Web; click for information
電子資源:
http://www.engineeringvillage.com/controller/servlet/OpenURL?genre=book&isbn=9780444521866
電子資源:
http://www.loc.gov/catdir/enhancements/fy0664/2006050248-d.html
ISBN:
9780444521866
Chemical kineticsfrom molecular structure to chemical reactivity /
Arnaut, Lu�is G.,1960-
Chemical kinetics
from molecular structure to chemical reactivity /[electronic resource] :Luis Arnaut, Sebastiao Formosinho, Hugh Burrows. - 1st ed. - Amsterdam ;Elsevier,2007. - xii, 549 p. :ill. ;25 cm.
Includes bibliographical references and index.
1. Introduction -- 2. Reaction rate laws -- 3. Experimental methods -- 4. Rate constants and reaction orders -- 5. Collisions and molecular dynamics -- 6. Reactivity in thermalized systems -- 7. Structure-Reactivity Relationships -- 8. Unimolecular Reactions -- 9. Reaction in solution -- 10. Reactions in surfaces -- 11. Nucleophilic substitution reactions -- 12. Chain reactions -- 13. Acid-base catalysis and proton-transfer reactions -- 14. Enzyme catalysis -- 15. Transitions between electronic states -- 16. Electron transfers -- 17. Fractals, chaos and oscillatory reactions.
Chemical Kinetics bridges the gap between beginner and specialist with a path that leads the reader from the phenomenological approach to the rates of chemical reactions to the state-of-the-art calculation of the rate constants of the most prevalent reactions: atom transfers, catalysis, proton transfers, substitution reactions, energy transfers and electron transfers. For the beginner provides the basics: the simplest concepts, the fundamental experiments, and the underlying theories. For the specialist shows where sophisticated experimental and theoretical methods combine to offer a panorama of time-dependent molecular phenomena connected by a new rational. Chemical Kinetics goes far beyond the qualitative description: with the guidance of theory, the path becomes a reaction path that can actually be inspected and calculated. But Chemical Kinetics is more about structure and reactivity than numbers and calculations. A great emphasis in the clarity of the concepts is achieved by illustrating all the theories and mechanisms with recent examples, some of them described with sufficient detail and simplicity to be used in general chemistry and lab courses. * Looking at atoms and molecules, and how molecular structures change with time. * Providing practical examples and detailed theoretical calculations * Of special interest to Industrial Chemistry and Biochemistry.
Electronic reproduction.
Amsterdam :
Elsevier Science & Technology,
2007.
Mode of access: World Wide Web.
ISBN: 9780444521866
Source: 117082:117184Elsevier Science & Technologyhttp://www.sciencedirect.comSubjects--Topical Terms:
193661
Chemical kinetics.
Index Terms--Genre/Form:
214472
Electronic books.
LC Class. No.: QD502 / .A76 2007eb
Dewey Class. No.: 541/.394
National Agricultural Library Call No.: QD502 / .A76 2007
Chemical kineticsfrom molecular structure to chemical reactivity /
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1. Introduction -- 2. Reaction rate laws -- 3. Experimental methods -- 4. Rate constants and reaction orders -- 5. Collisions and molecular dynamics -- 6. Reactivity in thermalized systems -- 7. Structure-Reactivity Relationships -- 8. Unimolecular Reactions -- 9. Reaction in solution -- 10. Reactions in surfaces -- 11. Nucleophilic substitution reactions -- 12. Chain reactions -- 13. Acid-base catalysis and proton-transfer reactions -- 14. Enzyme catalysis -- 15. Transitions between electronic states -- 16. Electron transfers -- 17. Fractals, chaos and oscillatory reactions.
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Reaction rate laws -- Experimental methods -- Reaction order and rate constants -- Collisions and molecular dynamics -- Reactivity in thermalised systems -- Relationships between structure and reactivity -- Unimolecular reactions -- Elementary reactions in solution -- Reactions on surfaces -- Substitution reactions -- Chain reactions -- Acid-base catalysis and proton-transfer reactions -- Enzymatic catalysis -- Transitions between electronic states -- Electron transfer reactions -- Appendix I. General data -- Appendix II. Statistical Thermodynamics -- Appendix III. Parameters employed in ISM calculations -- Appendix IV. Semi-classical interacting state model -- Appendix V. The Lippincott-Schroeder Potential.
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Chemical Kinetics bridges the gap between beginner and specialist with a path that leads the reader from the phenomenological approach to the rates of chemical reactions to the state-of-the-art calculation of the rate constants of the most prevalent reactions: atom transfers, catalysis, proton transfers, substitution reactions, energy transfers and electron transfers. For the beginner provides the basics: the simplest concepts, the fundamental experiments, and the underlying theories. For the specialist shows where sophisticated experimental and theoretical methods combine to offer a panorama of time-dependent molecular phenomena connected by a new rational. Chemical Kinetics goes far beyond the qualitative description: with the guidance of theory, the path becomes a reaction path that can actually be inspected and calculated. But Chemical Kinetics is more about structure and reactivity than numbers and calculations. A great emphasis in the clarity of the concepts is achieved by illustrating all the theories and mechanisms with recent examples, some of them described with sufficient detail and simplicity to be used in general chemistry and lab courses. * Looking at atoms and molecules, and how molecular structures change with time. * Providing practical examples and detailed theoretical calculations * Of special interest to Industrial Chemistry and Biochemistry.
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http://www.engineeringvillage.com/controller/servlet/OpenURL?genre=book&isbn=9780444521866
http://www.loc.gov/catdir/enhancements/fy0664/2006050248-d.html
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