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三苯胺/乙烯二氧噻吩系全有機染料太陽能電池 = Triphenylami...

國立高雄大學化學工程及材料工程學系碩士班

三苯胺/乙烯二氧噻吩系全有機染料太陽能電池 = Triphenylamine-Ethlenedioxythiophene-based Organic Dye-Sensitized Solar Cells

紀錄類型:	書目-語言資料,印刷品 : 單行本
並列題名:	Triphenylamine-Ethlenedioxythiophene-based Organic Dye-Sensitized Solar Cells
作者:	孫宇光,
其他團體作者:	國立高雄大學
出版地:	[高雄市]
出版者:	撰者;
出版年:	民100
面頁冊數:	120葉圖，表格 : 30公分;
標題:	染料敏化太陽能電池
標題:	tripenylamine
電子資源:	http://handle.ncl.edu.tw/11296/ndltd/98280651032449455005
附註:	參考書目：葉101-107
摘要註:	本研究主要是合成以三苯胺(triphenylamin ， TPA) 鍵結乙烯二氧噻吩(3,4-ethylenedioxythiophene)結構之全有機小分子光敏化染料，全有機小分子染料相較於市售釕金屬錯合物染料，有著高吸收系數、設計性佳與不需使用貴重金屬元素…等優點。本研究以 TPA 有三個對位易反應位置做探討，文獻中常只對 TPA 接上一個電子受體做為染料結構，因此為了要瞭解 TPA 最佳分子結構模型，對 TPA 鍵結(Z)-2-cyano-3-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)acrylic acid 在其對位上，並且依鍵結數量分為 ETPA1(鍵結1個)、ETPA2(鍵結2個)與ETPA3(鍵結2個以及1個carbazole)，即可得到donor-bridge-acceptor結構之有機小分子光敏化染料，並利用 cyanoacetic acid上之羧酸和二氧化鈦奈米粒子螯合後，對其做光學、電學與光電轉換效率的測量；同時將有類似 ETPA3 結構的CTPAR2(電子受體部分以 rhodanine-3-acetic acid 取代)，比較基團的優異性，以及染料分子的設計差異( bridge 的導入)。染料 ETPA3 效率可達5.20%。 In this study, light-sensitive and all-organic of dye molecules have been synthesized bytriphenylamine linked with 3,4-ethylenedioxythiophene structure. All-organic dye molecules,compared to the commercially-available ruthenium-based complexe type, hvae a highabsorption coefficient, the designable and metal-free. Triphenylamine has tree para-positionswith can be replaced by reaction. However, it was found in the literature that triphenylaminewas usually connected to an electron acceptor only. In order to understand the best structuremodel of triphenylamine, (Z)-2-cyano-3-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl) acrylicacid was linked to triphenylamine of para-positions, the para-position substitutedtriphenylamine were divided into ETPA1(one function group), ETPA2(two function group)and ETPA3(two function groups and one carbazole group) according to the number ofsubstitutions. The photosensitive organic dye molecules were donor-brige-acceptor structure,and chelated titanium dioxide nanoparticles by the carboxylic groups of cyanoacetic acid.Optical, electrical and photoelectric conversion efficiency are measured. The synthetic dyesof ETPA3 structure was compared with CTPAR2(electron acceptor part be replaced by therodanine-3-acetic acid) has better efficiency(brige was introduced). The optimal efficiency ofDSSCs reaches to 5.20% for ETPA3 dye

三苯胺/乙烯二氧噻吩系全有機染料太陽能電池 = Triphenylamine-Ethlenedioxythiophene-based Organic Dye-Sensitized Solar Cells
孫, 宇光

三苯胺/乙烯二氧噻吩系全有機染料太陽能電池 = Triphenylamine-Ethlenedioxythiophene-based Organic Dye-Sensitized Solar Cells / 孫宇光撰 - [高雄市] : 撰者, 民100. - 120葉 ; 圖，表格 ; 30公分.
參考書目：葉101-107.
染料敏化太陽能電池tripenylamine

三苯胺/乙烯二氧噻吩系全有機染料太陽能電池 = Triphenylamine-Ethlenedioxythiophene-based Organic Dye-Sensitized Solar Cells
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330 $a 本研究主要是合成以三苯胺(triphenylamin ， TPA) 鍵結乙烯二氧噻吩(3,4-ethylenedioxythiophene)結構之全有機小分子光敏化染料，全有機小分子染料相較於市售釕金屬錯合物染料，有著高吸收系數、設計性佳與不需使用貴重金屬元素…等優點。本研究以 TPA 有三個對位易反應位置做探討，文獻中常只對 TPA 接上一個電子受體做為染料結構，因此為了要瞭解 TPA 最佳分子結構模型，對 TPA 鍵結(Z)-2-cyano-3-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)acrylic acid 在其對位上，並且依鍵結數量分為 ETPA1(鍵結1個)、ETPA2(鍵結2個)與ETPA3(鍵結2個以及1個carbazole)，即可得到donor-bridge-acceptor結構之有機小分子光敏化染料，並利用 cyanoacetic acid上之羧酸和二氧化鈦奈米粒子螯合後，對其做光學、電學與光電轉換效率的測量；同時將有類似 ETPA3 結構的CTPAR2(電子受體部分以 rhodanine-3-acetic acid 取代)，比較基團的優異性，以及染料分子的設計差異( bridge 的導入)。染料 ETPA3 效率可達5.20%。 In this study, light-sensitive and all-organic of dye molecules have been synthesized bytriphenylamine linked with 3,4-ethylenedioxythiophene structure. All-organic dye molecules,compared to the commercially-available ruthenium-based complexe type, hvae a highabsorption coefficient, the designable and metal-free. Triphenylamine has tree para-positionswith can be replaced by reaction. However, it was found in the literature that triphenylaminewas usually connected to an electron acceptor only. In order to understand the best structuremodel of triphenylamine, (Z)-2-cyano-3-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl) acrylicacid was linked to triphenylamine of para-positions, the para-position substitutedtriphenylamine were divided into ETPA1(one function group), ETPA2(two function group)and ETPA3(two function groups and one carbazole group) according to the number ofsubstitutions. The photosensitive organic dye molecules were donor-brige-acceptor structure,and chelated titanium dioxide nanoparticles by the carboxylic groups of cyanoacetic acid.Optical, electrical and photoelectric conversion efficiency are measured. The synthetic dyesof ETPA3 structure was compared with CTPAR2(electron acceptor part be replaced by therodanine-3-acetic acid) has better efficiency(brige was introduced). The optimal efficiency ofDSSCs reaches to 5.20% for ETPA3 dye
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