國立高雄大學圖資館 |

Language: English

Back

全固態染料敏化太陽能電池製作與三苯胺系列染料合成 = Fabricati...

國立高雄大學化學工程及材料工程學系碩士班

全固態染料敏化太陽能電池製作與三苯胺系列染料合成 = Fabrication of all-solid-state dye-sensitized solar cells and synthesis of triphenylamine-based organic dyes

Record Type:	Language materials, printed : monographic
Paralel Title:	Fabrication of all-solid-state dye-sensitized solar cells and synthesis of triphenylamine-based organic dyes
Author:	潘俞均,
Secondary Intellectual Responsibility:	國立高雄大學
Place of Publication:	[高雄市]
Published:	撰者;
Year of Publication:	2012[民101]
Description:	146面圖，表格 : 30公分;
Subject:	三苯胺
Subject:	Triphenylamine
Online resource:	http://handle.ncl.edu.tw/11296/ndltd/20787190009279462766
Notes:	參考書目：面124-132
Summary:	本研究主要是合成以三苯胺（Triphenylamine，TPA）鍵結1-甲基吡咯（N-Methylpyrrole）結構之全有機小分子光敏化染料，全有機染料相較於市售釕金屬錯合物染料，有高吸收係數、設計性佳與不需使用貴重金屬元素等優點。研究中運用了 Vilsmeier–Haack 反應、溴化反應、 Kumada 偶合反應、 Suzuki 偶合反應及 Knoevenagel 縮合反應來合成我們全有機小分子光敏化染料，並利用Cyanoacetic acid和二氧化鈦奈米粒子進行螯合作用，對其作光學、電學及光電轉換效率的測量。MTPA1染料結構其最佳效率可達 0.34 %。另一方面，使用聚（3-己基噻吩）（Poly(3-hexylthiophene)，P3HT）當電洞傳導層製作全固態染料敏化太陽能電池，比較市售有機染料（N3、D131及D149）與無機染料（Sb2S3）的效率。N3 染料結構其最佳效率可達 2.48 %。 In this study, light-sensitive and all-organic of dye molecules have been synthesized by triphenylamine linked with N-Methylpyrrole structure. All-organic dye molecules, compared to the commercially-available ruthenium-based complexe type, hvae the advantages of high absorption coefficient, the designable and metal-free. We made use of the Vilsmeier-Haack reaction, bromination, Kumada coupling reaction, Suzuki coupling reaction and Knoevenagel condensation reaction for the photosensitive organic dye molecules. We chelated titanium dioxide nanoparticles by the groups of cyanoacetic acid. And then Optical, electrical and photoelectric conversion efficiency were measured. The optimal efficiency of DSSCs reaches to 0.34% for MTPA1 dye. In addition, We fabricated all-solid-state dye-sensitized solar cells and used Poly(3-hexylthiophene) as the Hole Transfer Materials. We compared the photoelectric conversion efficiency of the market organic dye (N3, D131 and D149) with the inorganic dye (Sb2S3).The optimal efficiency of DSSCs reaches to 2.48% for N3 dye.

全固態染料敏化太陽能電池製作與三苯胺系列染料合成 = Fabrication of all-solid-state dye-sensitized solar cells and synthesis of triphenylamine-based organic dyes
潘, 俞均

全固態染料敏化太陽能電池製作與三苯胺系列染料合成 = Fabrication of all-solid-state dye-sensitized solar cells and synthesis of triphenylamine-based organic dyes / 潘俞均撰 - [高雄市] : 撰者, 2012[民101]. - 146面 ; 圖，表格 ; 30公分.
參考書目：面124-132.
三苯胺Triphenylamine

全固態染料敏化太陽能電池製作與三苯胺系列染料合成 = Fabrication of all-solid-state dye-sensitized solar cells and synthesis of triphenylamine-based organic dyes
LDR:03292nam0a2200277 450 001 345995
005 20170214092624.0
009 345995
010 0 $b 精裝
010 0 $b 平裝
100 $a 20170214d2012 k y0chiy05 e
101 1 $a chi $d chi $d eng
102 $a tw
105 $a ak am 000yy
200 1 $a 全固態染料敏化太陽能電池製作與三苯胺系列染料合成 $d Fabrication of all-solid-state dye-sensitized solar cells and synthesis of triphenylamine-based organic dyes $z eng $f 潘俞均撰
210 $a [高雄市] $c 撰者 $d 2012[民101]
215 0 $a 146面 $c 圖，表格 $d 30公分
300 $a 參考書目：面124-132
314 $a 指導教授：楊乾信教授
328 $a 碩士論文--國立高雄大學化學工程及材料工程學系碩士班
330 $a 本研究主要是合成以三苯胺（Triphenylamine，TPA）鍵結1-甲基吡咯（N-Methylpyrrole）結構之全有機小分子光敏化染料，全有機染料相較於市售釕金屬錯合物染料，有高吸收係數、設計性佳與不需使用貴重金屬元素等優點。研究中運用了 Vilsmeier–Haack 反應、溴化反應、 Kumada 偶合反應、 Suzuki 偶合反應及 Knoevenagel 縮合反應來合成我們全有機小分子光敏化染料，並利用Cyanoacetic acid和二氧化鈦奈米粒子進行螯合作用，對其作光學、電學及光電轉換效率的測量。MTPA1染料結構其最佳效率可達 0.34 %。另一方面，使用聚（3-己基噻吩）（Poly(3-hexylthiophene)，P3HT）當電洞傳導層製作全固態染料敏化太陽能電池，比較市售有機染料（N3、D131及D149）與無機染料（Sb2S3）的效率。N3 染料結構其最佳效率可達 2.48 %。 In this study, light-sensitive and all-organic of dye molecules have been synthesized by triphenylamine linked with N-Methylpyrrole structure. All-organic dye molecules, compared to the commercially-available ruthenium-based complexe type, hvae the advantages of high absorption coefficient, the designable and metal-free. We made use of the Vilsmeier-Haack reaction, bromination, Kumada coupling reaction, Suzuki coupling reaction and Knoevenagel condensation reaction for the photosensitive organic dye molecules. We chelated titanium dioxide nanoparticles by the groups of cyanoacetic acid. And then Optical, electrical and photoelectric conversion efficiency were measured. The optimal efficiency of DSSCs reaches to 0.34% for MTPA1 dye. In addition, We fabricated all-solid-state dye-sensitized solar cells and used Poly(3-hexylthiophene) as the Hole Transfer Materials. We compared the photoelectric conversion efficiency of the market organic dye (N3, D131 and D149) with the inorganic dye (Sb2S3).The optimal efficiency of DSSCs reaches to 2.48% for N3 dye.
510 1 $a Fabrication of all-solid-state dye-sensitized solar cells and synthesis of triphenylamine-based organic dyes $z eng
610 0 $a 三苯胺 $a 1-甲基吡咯 $a 染料敏化太陽能電池 $a 全固態染料敏化太陽能電池
610 1 $a Triphenylamine $a N-Methylpyrrole $a Dye-Sensitized Solar Cells $a All-solid-state Dye-Sensitized Solar Cells
681 $a 008M/0019 $b 541208 3284 $v 2007年版
700 1 $a 潘 $b 俞均 $4 撰 $3 576235
712 0 2 $a 國立高雄大學 $b 化學工程及材料工程學系碩士班 $3 353898
801 0 $a tw $b NUK $c 20121108 $g CCR
856 7 $z 電子資源 $2 http $u http://handle.ncl.edu.tw/11296/ndltd/20787190009279462766