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The properties of water and their ro...

Van Oss, Carel J.

The properties of water and their role in colloidal and biological systems

Record Type:	Electronic resources : Monograph/item
Title/Author:	The properties of water and their role in colloidal and biological systemsCarel Jan van Oss.
Author:	Van Oss, Carel J.
Published:	Amsterdam ;Elsevier/Academic Press,2008.
Description:	1 online resource (xiv, 224 p.) :ill.
Subject:	WaterAnalysis.
Online resource:	http://www.sciencedirect.com/science/book/9780123743039
ISBN:	9780123743039

The properties of water and their role in colloidal and biological systems
Van Oss, Carel J.

The properties of water and their role in colloidal and biological systems[electronic resource] /Carel Jan van Oss. - Amsterdam ;Elsevier/Academic Press,2008. - 1 online resource (xiv, 224 p.) :ill. - Interface science and technology ;v. 16. - Interface science and technology ;v. 17..

Includes bibliographical references and index.

SECTION A. NON-COVALENT ENERGIES OF INTERACTION -- EQUATIONS AND COMBINING RULES -- SECTION B: SURFACE THERMODYNAMIC PROPERTIES OF WATER WITH RESPECT TO CONDENSED-PHASE MATERIALS IMMERSED IN IT -- SECTION C: PHYSICAL AND PHYSICOCHEMICAL PROPERTIES OF WATER.

This book treats the different current as well as unusual and hitherto often unstudied physico-chemical and surface-thermodynamic properties of water that govern all polar interactions occurring in it. These properties include the hyper-hydrophobicity of the water-air interface, the cluster formation of water molecules in the liquid state and the concomitant variability of the ratio of the electron-accepticity to electron-donicity of liquid water as a function of temperature, T. The increase of that ratio with T is the cause of the increase in hydration repulsion (hydration pressure) between polar surfaces upon heating, when they are immersed in water. The book also treats the surface properties of apolar and polar molecules, polymers, particles and cells, as well as their mutual interaction energies, when immersed in water, under the influence of the three prevailing non-covalent forces, i.e., Lewis acid-base (AB), Lifshitz-van der Waals (LW) and electrical double layer (EL) interactions. The polar AB interactions, be they attractive or repulsive, typically represent up to 90% of the total interaction energies occurring in water. Thus the addition of AB energies to the LW + EL energies of the classical DLVO theory of energy vs. distance analysis makes this powerful tool (the Extended DLVO theory) applicable to the quantitative study of the stability of particle suspensions in water. The influence of AB forces on the interfacial tension between water and other condensed-phase materials is stressed and serves, inter alia, to explain, measure and calculate the driving force of the hydrophobic attraction between such materials (the b3 shydrophobic effect b4 s), when immersed in water. These phenomena, which are typical for liquid water, influence all polar interactions that take place in it. All of these are treated from the viewpoint of the properties of liquid water itself, including the properties of advancing freezing fronts and the surface properties of ice at 0o C. - Explains and allows the quantitative measurement of hydrophobic attraction and hydrophilic repulsion in water. Measures the degree of cluster formation of water molecules. Discusses the influence of temperature on the cluster size of water molecules. Treats the multitudinous effects of the hyper-hydrophobicity of the water-air interface.

ISBN: 9780123743039

Source: 132964:133087Elsevier Science & Technologyhttp://www.sciencedirect.comSubjects--Topical Terms:

586198
Water
--Analysis.Index Terms--Genre/Form:

214472
Electronic books.

LC Class. No.: QD169.W3 / V36 2008

Dewey Class. No.: 546.22

The properties of water and their role in colloidal and biological systems
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504 $a Includes bibliographical references and index.
505 0 $a SECTION A. NON-COVALENT ENERGIES OF INTERACTION -- EQUATIONS AND COMBINING RULES -- SECTION B: SURFACE THERMODYNAMIC PROPERTIES OF WATER WITH RESPECT TO CONDENSED-PHASE MATERIALS IMMERSED IN IT -- SECTION C: PHYSICAL AND PHYSICOCHEMICAL PROPERTIES OF WATER.
520 $a This book treats the different current as well as unusual and hitherto often unstudied physico-chemical and surface-thermodynamic properties of water that govern all polar interactions occurring in it. These properties include the hyper-hydrophobicity of the water-air interface, the cluster formation of water molecules in the liquid state and the concomitant variability of the ratio of the electron-accepticity to electron-donicity of liquid water as a function of temperature, T. The increase of that ratio with T is the cause of the increase in hydration repulsion (hydration pressure) between polar surfaces upon heating, when they are immersed in water. The book also treats the surface properties of apolar and polar molecules, polymers, particles and cells, as well as their mutual interaction energies, when immersed in water, under the influence of the three prevailing non-covalent forces, i.e., Lewis acid-base (AB), Lifshitz-van der Waals (LW) and electrical double layer (EL) interactions. The polar AB interactions, be they attractive or repulsive, typically represent up to 90% of the total interaction energies occurring in water. Thus the addition of AB energies to the LW + EL energies of the classical DLVO theory of energy vs. distance analysis makes this powerful tool (the Extended DLVO theory) applicable to the quantitative study of the stability of particle suspensions in water. The influence of AB forces on the interfacial tension between water and other condensed-phase materials is stressed and serves, inter alia, to explain, measure and calculate the driving force of the hydrophobic attraction between such materials (the b3 shydrophobic effect b4 s), when immersed in water. These phenomena, which are typical for liquid water, influence all polar interactions that take place in it. All of these are treated from the viewpoint of the properties of liquid water itself, including the properties of advancing freezing fronts and the surface properties of ice at 0o C. - Explains and allows the quantitative measurement of hydrophobic attraction and hydrophilic repulsion in water. Measures the degree of cluster formation of water molecules. Discusses the influence of temperature on the cluster size of water molecules. Treats the multitudinous effects of the hyper-hydrophobicity of the water-air interface.
588 $a Description based on print version record.
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650 0 $a Water $x Properties. $3 586225
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830 0 $a Interface science and technology ; $v v. 17. $3 454190
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