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醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究 = A study on to...

國立高雄大學化學工程及材料工程學系碩士班

醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究 = A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid

Record Type:	Language materials, printed : monographic
Paralel Title:	A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid
Author:	張聖雄,
Secondary Intellectual Responsibility:	國立高雄大學
Place of Publication:	[高雄市]
Published:	撰者;
Year of Publication:	2014[民103]
Description:	90面圖，表 : 30公分;
Subject:	環氧樹脂
Subject:	Epoxy resin
Online resource:	http://handle.ncl.edu.tw/11296/ndltd/19651977717845722544
Notes:	參考書目：面76-79
Notes:	103年12月16日公開
Summary:	環氧樹脂(epoxy resin)為應用非常廣泛的熱固性樹脂，但耐衝擊性能差，無法全面滿足工程上的要求。本研究以聚脂肪二酸(dimer fatty acid)和聚醚二胺(polyetherdiamine)行聚縮合反應，製備出醚醯胺化聚脂肪二酸之增韌改質劑，然後加入環氧樹脂中，調配成90/10、80/20、70/30、60/40 (環氧樹脂/增韌改質劑重量比)，藉由開環加成反應，使增韌改質劑以共價鍵結方式導入環氧樹脂分子結構中。實驗結果發現，硬化後環氧樹脂表面硬度、抗拉強度與抗拉模數均隨著增韌改質劑的增加而下降，抗衝擊強度與韌性則隨著增韌改質劑增加而上升，特別是在增韌改質劑添加量達到40 wt%時，增韌效果最為明顯，且未發現有相分離現象。 Epoxy resin is a widely used thermosetting resin but has poor impact resistance in some applications. In this study, carboxyl-terminated poly(ether-amide) was prepared by condensation reactions of a commercialized dicarboxylic acid and a commercialized poly(ether diamine) and was used as a toughening agent. The so-prepared toughening agent was then added into epoxy resin to have four different weight ratios of epoxy resin/toughening agent including 90/10, 80/20, 70/30, and 60/40.Upon curing at elevated temperatures, the toughening agent can be covalently incorporated into the epoxy resin via ring-opening reactions of the epoxide groups. The results found that the surface hardness, tensile strength, and Young’s modulus decreased with increasing contents of the toughening agent; the toughness and impact strength, however, increased with increasing contents of the toughening agent. In particular, the epoxy resin containing 40 wt% toughening agent exhibited the highest toughening effect without phase separations.

醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究 = A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid
張, 聖雄

醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究 = A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid / 張聖雄撰 - [高雄市] : 撰者, 2014[民103]. - 90面 ; 圖，表 ; 30公分.
參考書目：面76-79103年12月16日公開.
環氧樹脂Epoxy resin

醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究 = A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid
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200 1 $a 醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究 $d A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid $z eng $f 張聖雄撰
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300 $a 參考書目：面76-79
300 $a 103年12月16日公開
314 $a 指導教授：謝永堂博士
328 $a 碩士論文--國立高雄大學化學工程及材料工程學系碩士班
330 $a 環氧樹脂(epoxy resin)為應用非常廣泛的熱固性樹脂，但耐衝擊性能差，無法全面滿足工程上的要求。本研究以聚脂肪二酸(dimer fatty acid)和聚醚二胺(polyetherdiamine)行聚縮合反應，製備出醚醯胺化聚脂肪二酸之增韌改質劑，然後加入環氧樹脂中，調配成90/10、80/20、70/30、60/40 (環氧樹脂/增韌改質劑重量比)，藉由開環加成反應，使增韌改質劑以共價鍵結方式導入環氧樹脂分子結構中。實驗結果發現，硬化後環氧樹脂表面硬度、抗拉強度與抗拉模數均隨著增韌改質劑的增加而下降，抗衝擊強度與韌性則隨著增韌改質劑增加而上升，特別是在增韌改質劑添加量達到40 wt%時，增韌效果最為明顯，且未發現有相分離現象。 Epoxy resin is a widely used thermosetting resin but has poor impact resistance in some applications. In this study, carboxyl-terminated poly(ether-amide) was prepared by condensation reactions of a commercialized dicarboxylic acid and a commercialized poly(ether diamine) and was used as a toughening agent. The so-prepared toughening agent was then added into epoxy resin to have four different weight ratios of epoxy resin/toughening agent including 90/10, 80/20, 70/30, and 60/40.Upon curing at elevated temperatures, the toughening agent can be covalently incorporated into the epoxy resin via ring-opening reactions of the epoxide groups. The results found that the surface hardness, tensile strength, and Young’s modulus decreased with increasing contents of the toughening agent; the toughness and impact strength, however, increased with increasing contents of the toughening agent. In particular, the epoxy resin containing 40 wt% toughening agent exhibited the highest toughening effect without phase separations.
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