語系:
繁體中文
English
說明(常見問題)
圖資館首頁
登入
回首頁
切換:
標籤
|
MARC模式
|
ISBD
醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究 = A study on to...
~
國立高雄大學化學工程及材料工程學系碩士班
醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究 = A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid
紀錄類型:
書目-語言資料,印刷品 : 單行本
並列題名:
A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid
作者:
張聖雄,
其他團體作者:
國立高雄大學
出版地:
[高雄市]
出版者:
撰者;
出版年:
2014[民103]
面頁冊數:
90面圖,表 : 30公分;
標題:
環氧樹脂
標題:
Epoxy resin
電子資源:
http://handle.ncl.edu.tw/11296/ndltd/19651977717845722544
附註:
參考書目:面76-79
附註:
103年12月16日公開
摘要註:
環氧樹脂(epoxy resin)為應用非常廣泛的熱固性樹脂,但耐衝擊性能差,無法全面滿足工程上的要求。本研究以聚脂肪二酸(dimer fatty acid)和聚醚二胺(polyetherdiamine)行聚縮合反應,製備出醚醯胺化聚脂肪二酸之增韌改質劑,然後加入環氧樹脂中,調配成90/10、80/20、70/30、60/40 (環氧樹脂/增韌改質劑 重量比),藉由開環加成反應,使增韌改質劑以共價鍵結方式導入環氧樹脂分子結構中。實驗結果發現,硬化後環氧樹脂表面硬度、抗拉強度與抗拉模數均隨著增韌改質劑的增加而下降,抗衝擊強度與韌性則隨著增韌改質劑增加而上升,特別是在增韌改質劑添加量達到40 wt%時,增韌效果最為明顯,且未發現有相分離現象。 Epoxy resin is a widely used thermosetting resin but has poor impact resistance in some applications. In this study, carboxyl-terminated poly(ether-amide) was prepared by condensation reactions of a commercialized dicarboxylic acid and a commercialized poly(ether diamine) and was used as a toughening agent. The so-prepared toughening agent was then added into epoxy resin to have four different weight ratios of epoxy resin/toughening agent including 90/10, 80/20, 70/30, and 60/40.Upon curing at elevated temperatures, the toughening agent can be covalently incorporated into the epoxy resin via ring-opening reactions of the epoxide groups. The results found that the surface hardness, tensile strength, and Young’s modulus decreased with increasing contents of the toughening agent; the toughness and impact strength, however, increased with increasing contents of the toughening agent. In particular, the epoxy resin containing 40 wt% toughening agent exhibited the highest toughening effect without phase separations.
醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究 = A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid
張, 聖雄
醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究
= A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid / 張聖雄撰 - [高雄市] : 撰者, 2014[民103]. - 90面 ; 圖,表 ; 30公分.
參考書目:面76-79103年12月16日公開.
環氧樹脂Epoxy resin
醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究 = A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid
LDR
:03088nam0a2200289 450
001
429876
005
20170214101050.0
009
429876
010
0
$b
精裝
010
0
$b
平裝
100
$a
20170214d2014 k y0chiy05 e
101
1
$a
chi
$d
chi
$d
eng
102
$a
tw
105
$a
ak am 000yy
200
1
$a
醚醯胺化聚脂肪二酸增韌改質環氧樹脂之研究
$d
A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid
$z
eng
$f
張聖雄撰
210
$a
[高雄市]
$c
撰者
$d
2014[民103]
215
0
$a
90面
$c
圖,表
$d
30公分
300
$a
參考書目:面76-79
300
$a
103年12月16日公開
314
$a
指導教授:謝永堂博士
328
$a
碩士論文--國立高雄大學化學工程及材料工程學系碩士班
330
$a
環氧樹脂(epoxy resin)為應用非常廣泛的熱固性樹脂,但耐衝擊性能差,無法全面滿足工程上的要求。本研究以聚脂肪二酸(dimer fatty acid)和聚醚二胺(polyetherdiamine)行聚縮合反應,製備出醚醯胺化聚脂肪二酸之增韌改質劑,然後加入環氧樹脂中,調配成90/10、80/20、70/30、60/40 (環氧樹脂/增韌改質劑 重量比),藉由開環加成反應,使增韌改質劑以共價鍵結方式導入環氧樹脂分子結構中。實驗結果發現,硬化後環氧樹脂表面硬度、抗拉強度與抗拉模數均隨著增韌改質劑的增加而下降,抗衝擊強度與韌性則隨著增韌改質劑增加而上升,特別是在增韌改質劑添加量達到40 wt%時,增韌效果最為明顯,且未發現有相分離現象。 Epoxy resin is a widely used thermosetting resin but has poor impact resistance in some applications. In this study, carboxyl-terminated poly(ether-amide) was prepared by condensation reactions of a commercialized dicarboxylic acid and a commercialized poly(ether diamine) and was used as a toughening agent. The so-prepared toughening agent was then added into epoxy resin to have four different weight ratios of epoxy resin/toughening agent including 90/10, 80/20, 70/30, and 60/40.Upon curing at elevated temperatures, the toughening agent can be covalently incorporated into the epoxy resin via ring-opening reactions of the epoxide groups. The results found that the surface hardness, tensile strength, and Young’s modulus decreased with increasing contents of the toughening agent; the toughness and impact strength, however, increased with increasing contents of the toughening agent. In particular, the epoxy resin containing 40 wt% toughening agent exhibited the highest toughening effect without phase separations.
510
1
$a
A study on toughness of epoxy resin improved by carboxyl-terminated poly(ether-amide) fatty acid
$z
eng
610
0
$a
環氧樹脂
$a
衝擊強度
$a
增韌劑
$a
醚醯胺化聚脂肪二酸
610
1
$a
Epoxy resin
$a
impact strength
$a
toughening agent
$a
carboxyl-terminated poly(ether-amide)
681
$a
008M/0019
$b
541208 1114
$v
2007年版
700
1
$a
張
$b
聖雄
$4
撰
$3
673135
712
0 2
$a
國立高雄大學
$b
化學工程及材料工程學系碩士班
$3
353898
801
0
$a
tw
$b
NUK
$c
20141021
$g
CCR
856
7
$z
電子資源
$2
http
$u
http://handle.ncl.edu.tw/11296/ndltd/19651977717845722544
筆 0 讀者評論
全部
博碩士論文區(二樓)
館藏
2 筆 • 頁數 1 •
1
條碼號
館藏地
館藏流通類別
資料類型
索書號
使用類型
借閱狀態
預約狀態
備註欄
附件
310002500349
博碩士論文區(二樓)
不外借資料
學位論文
TH 008M/0019 541208 1114 2014
一般使用(Normal)
在架
0
310002500356
博碩士論文區(二樓)
不外借資料
學位論文
TH 008M/0019 541208 1114 2014 c.2
一般使用(Normal)
在架
0
2 筆 • 頁數 1 •
1
多媒體
多媒體檔案
http://handle.ncl.edu.tw/11296/ndltd/19651977717845722544
評論
新增評論
分享你的心得
Export
取書館別
處理中
...
變更密碼
登入