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三苯胺/苯乙烯系染料合成與其在敏化太陽能電池與電致變色元件之初步應用 =...

國立高雄大學化學工程及材料工程學系碩士班

三苯胺/苯乙烯系染料合成與其在敏化太陽能電池與電致變色元件之初步應用 = Synthesis of triphenylamine-styrene-based dyes and its application in sensitized solar cells and electrochromic devices

Record Type:	Language materials, printed : monographic
Paralel Title:	Synthesis of triphenylamine-styrene-based dyes and its application in sensitized solar cells and electrochromic devices
Author:	蘇元岑,
Secondary Intellectual Responsibility:	國立高雄大學
Place of Publication:	[高雄市]
Published:	撰者;
Year of Publication:	民103[2014]
Description:	101葉部分彩圖，表格 : 30公分;
Subject:	染料敏化太陽能電池
Subject:	Dye-sensitized solar cells
Online resource:	http://hdl.handle.net/11296/ndltd/77443164386069675816
Notes:	106年10月31日公開
Notes:	參考書目：葉93-101
Summary:	本研究主要是合成以三苯胺( tripenylamine，TPA) 與苯乙烯(styrene) 結構共價結合之全有機小分子光敏化染料，染料敏化太陽能電池中的染料為有機小分子時，相較於一般 Gratzel 太陽能電池常用之金屬錯合物染料，有著高吸收係數而不需使用貴重金屬元素的優點。本研究運用了 4 種有機合成方法，先以 Vilsmeier-Haack 反應將 TPA 分別接上 1 與 2 的 aldehyde 數目，利用 Witting reaction 把 –CHO 轉成 -CH=CH2，再利用 Mizoroki-Heck reaction 分別接上所需的 4-bromobenzaldehyde 當作架橋，最後利用 Knoevenagel condensation reaction 以將 TSC1 與 TSC2 共價結合物上之 aldehyde 進行親核性加成反應隨後再進行脫水反應，即可得到我們所需之全有機小分子光敏化染料。之後再以 rhodanine-3-acetic acid 與 2-isocyanoacetic acid 上之 carboxylic acids 和二氧化鈦奈米粒子進行螯合作用。分別探討接上不同數目的 4-bromobenzaldehyde 之染料組成染料敏化太陽能電池元件與電致色變元件的效能差異。 Linking organic dye small molecules are synthesized by linking triphenylamine with styrene structure. Four different methods were employed to synthesize：the Vilsmeier-Haack reaction to link one and two aldehyde groups respectively, the Mizoroki-Heck reaction to link 4-bromobenzaldehyde regarding as a bridge, and the nucleophilic addition and dehydration between the aldehyde groups on TSC1, TSC2, and the methylene of rhodanine-3-acetic acid or 2-isocyanoacetic acid individually by using the Knoevenagel condensation reaction. The above two dyes(STPACA and STPAR) are anchored on the surface of titanium dioxide nanoparticles via the carboxylic acid of dyes by using the self-assembly method. An integration of dye-sensitized solar cells and electrochromic devices was fabricated and subjected to measure the performance of these integrated devices.

三苯胺/苯乙烯系染料合成與其在敏化太陽能電池與電致變色元件之初步應用 = Synthesis of triphenylamine-styrene-based dyes and its application in sensitized solar cells and electrochromic devices
蘇, 元岑

三苯胺/苯乙烯系染料合成與其在敏化太陽能電池與電致變色元件之初步應用 = Synthesis of triphenylamine-styrene-based dyes and its application in sensitized solar cells and electrochromic devices / 蘇元岑撰 - [高雄市] : 撰者, 民103[2014]. - 101葉 ; 部分彩圖，表格 ; 30公分.
106年10月31日公開參考書目：葉93-101.
染料敏化太陽能電池Dye-sensitized solar cells

三苯胺/苯乙烯系染料合成與其在敏化太陽能電池與電致變色元件之初步應用 = Synthesis of triphenylamine-styrene-based dyes and its application in sensitized solar cells and electrochromic devices
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210 $a [高雄市] $c 撰者 $d 民103[2014]
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314 $a 指導教授：楊乾信博士
328 $a 碩士論文--國立高雄大學化學工程及材料工程學系碩士班
330 $a 本研究主要是合成以三苯胺( tripenylamine，TPA) 與苯乙烯(styrene) 結構共價結合之全有機小分子光敏化染料，染料敏化太陽能電池中的染料為有機小分子時，相較於一般 Gratzel 太陽能電池常用之金屬錯合物染料，有著高吸收係數而不需使用貴重金屬元素的優點。本研究運用了 4 種有機合成方法，先以 Vilsmeier-Haack 反應將 TPA 分別接上 1 與 2 的 aldehyde 數目，利用 Witting reaction 把 –CHO 轉成 -CH=CH2，再利用 Mizoroki-Heck reaction 分別接上所需的 4-bromobenzaldehyde 當作架橋，最後利用 Knoevenagel condensation reaction 以將 TSC1 與 TSC2 共價結合物上之 aldehyde 進行親核性加成反應隨後再進行脫水反應，即可得到我們所需之全有機小分子光敏化染料。之後再以 rhodanine-3-acetic acid 與 2-isocyanoacetic acid 上之 carboxylic acids 和二氧化鈦奈米粒子進行螯合作用。分別探討接上不同數目的 4-bromobenzaldehyde 之染料組成染料敏化太陽能電池元件與電致色變元件的效能差異。 Linking organic dye small molecules are synthesized by linking triphenylamine with styrene structure. Four different methods were employed to synthesize：the Vilsmeier-Haack reaction to link one and two aldehyde groups respectively, the Mizoroki-Heck reaction to link 4-bromobenzaldehyde regarding as a bridge, and the nucleophilic addition and dehydration between the aldehyde groups on TSC1, TSC2, and the methylene of rhodanine-3-acetic acid or 2-isocyanoacetic acid individually by using the Knoevenagel condensation reaction. The above two dyes(STPACA and STPAR) are anchored on the surface of titanium dioxide nanoparticles via the carboxylic acid of dyes by using the self-assembly method. An integration of dye-sensitized solar cells and electrochromic devices was fabricated and subjected to measure the performance of these integrated devices.
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610 # 1 $a Dye-sensitized solar cells $a Electrochromic devices $a Organic dye $a Tiphenylamine styrene-based dyes
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