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Hypervalent iodine reagents for tosy...

Klasen, Scott Clay.

Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis.
Author:	Klasen, Scott Clay.
Description:	127 p.
Notes:	Source: Masters Abstracts International, Volume: 55-02.
Notes:	Advisers: Viktor V. Zhdankin; Akira Yoshimura.
Contained By:	Masters Abstracts International55-02(E).
Subject:	Organic chemistry.
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1601585
ISBN:	9781339135090

Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis.
Klasen, Scott Clay.

Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis. - 127 p.

Source: Masters Abstracts International, Volume: 55-02.

Thesis (M.S.)--University of Minnesota, 2015.

In recent years, organohypervalent iodine compounds have emerged as environmentally friendly and efficient reagents for various synthetically useful oxidative transformations. The purpose of this research is to take a closer look at newer five membered heterocyclic hypervalent iodine compounds similar to the hydroxy(tosyloxy)iodobenzene (HTIB) studied by G.F. Koser in the 1980's, which utilized different variations of iodobenzene with different functional groups in the para-position of a benzene ring in order to perform ligand transfer reactions. Utilizing Koser's framework new heterocyclic hypervalent iodine reagents have been synthesized using 2-iodobenzoic acid as well as other similar substrates as a starting material along with HTIB. Different variations of these heterocycles have been synthesized in order to analyze the structural and kinetic nature of these less studied derivatives and their overall reactivity for selective oxidations and tosyl-transfer reactions in organic synthesis.*.

ISBN: 9781339135090Subjects--Topical Terms:

708640
Organic chemistry.

Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis.
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100 1 $a Klasen, Scott Clay. $3 730276
245 1 0 $a Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis.
300 $a 127 p.
500 $a Source: Masters Abstracts International, Volume: 55-02.
500 $a Advisers: Viktor V. Zhdankin; Akira Yoshimura.
502 $a Thesis (M.S.)--University of Minnesota, 2015.
520 $a In recent years, organohypervalent iodine compounds have emerged as environmentally friendly and efficient reagents for various synthetically useful oxidative transformations. The purpose of this research is to take a closer look at newer five membered heterocyclic hypervalent iodine compounds similar to the hydroxy(tosyloxy)iodobenzene (HTIB) studied by G.F. Koser in the 1980's, which utilized different variations of iodobenzene with different functional groups in the para-position of a benzene ring in order to perform ligand transfer reactions. Utilizing Koser's framework new heterocyclic hypervalent iodine reagents have been synthesized using 2-iodobenzoic acid as well as other similar substrates as a starting material along with HTIB. Different variations of these heterocycles have been synthesized in order to analyze the structural and kinetic nature of these less studied derivatives and their overall reactivity for selective oxidations and tosyl-transfer reactions in organic synthesis.*.
520 $a *Please refer to dissertation for diagrams.
590 $a School code: 0130.
650 4 $a Organic chemistry. $3 708640
650 4 $a Chemistry. $3 188628
690 $a 0490
690 $a 0485
710 2 $a University of Minnesota. $b Chemistry. $3 730277
773 0 $t Masters Abstracts International $g 55-02(E).
790 $a 0130
791 $a M.S.
792 $a 2015
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1601585