國立高雄大學圖資館 |

Language: English

Back

Organometallics for green catalysis

Dixneuf, Pierre H.

Organometallics for green catalysis

Record Type:	Electronic resources : Monograph/item
Title/Author:	Organometallics for green catalysisedited by Pierre H. Dixneuf, Jean-Francois Soule.
other author:	Dixneuf, Pierre H.
Published:	Cham :Springer International Publishing :2019.
Description:	x, 301 p. :ill., digital ;24 cm.
Contained By:	Springer eBooks
Subject:	Organometallic compounds.
Online resource:	https://doi.org/10.1007/978-3-030-10955-4
ISBN:	9783030109554$q(electronic bk.)

Organometallics for green catalysis
Organometallics for green catalysis[electronic resource] /edited by Pierre H. Dixneuf, Jean-Francois Soule. - Cham :Springer International Publishing :2019. - x, 301 p. :ill., digital ;24 cm. - Topics in organometallic chemistry,631436-6002 ;. - Topics in organometallic chemistry ;38.

Metal-Catalysed Hydrogenation of CO2 into Methanol -- Catalytic C-C Bond Formations from CO2 with Alkenes -- Recent advances on CO2 utilization as C1 building block in C-N and C-O bond formation -- "Alkene Metathesis for Transformation of Renewables" -- Metal-Catalyzed Aromatic C-O Bond Activation/Transformation -- Hydrogenation/Dehydrogenation of Unsaturated Bonds with Iron Pincer Catalysis -- Conversion of Alcohols to Carboxylates Using Water and Base with H2 Liberation -- Selective Transfer-hydrogenation of α,β-Unsaturated Carbonyl Compounds -- Functionalization of C(sp2)-H Bonds of Arenes and Heteroarenes Assisted by Photoredox-Catalysts for the C-C Bond Formation -- Green Cross-Coupling using Visible-light for C-O and C-N Bond Formation.

This volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The chemistry of carbon dioxide relating to its hydrogenation into methanol -an eco-friendly energy storage strategy- and its uses as C1 synthon for the formation of important building-blocks for fine chemicals industry are covered. Catalytic hydrogenations of various functional groups and hydrogen transfer reactions including the use of first row metal catalysts are presented as well as the conversion of alcohols to carboxylates via hydrogen transfer with a zero-waste strategy using water. Transformation of renewable or bio-based raw materials is surveyed through alkene metathesis and C-O bond activations and functionalizations. A green aspect for selective formation of C-C, C-O and C-N bonds involves direct regioselective C-H bond activations and functionalizations. These transformations can now be promoted under mild reaction conditions due to the use photoredox catalyts. C-H bond oxidation using visible light leads mainly to the formation of C-O and C-N bonds, whereas cross-coupled C-C bonds can be formed through the radical additions on (hetero) arenes using photoredox assisted mechanism.

ISBN: 9783030109554$q(electronic bk.)

Standard No.: 10.1007/978-3-030-10955-4doiSubjects--Topical Terms:

224541
Organometallic compounds.

LC Class. No.: QD411 / .O743 2019

Dewey Class. No.: 661.895

Organometallics for green catalysis
LDR:03155nmm a2200337 a 4500 001 553602
003 DE-He213
005 20190828135539.0
006 m d
007 cr nn 008maaau
008 191112s2019 gw s 0 eng d
020 $a 9783030109554$q(electronic bk.)
020 $a 9783030109547$q(paper)
024 7 $a 10.1007/978-3-030-10955-4 $2 doi
035 $a 978-3-030-10955-4
040 $a GP $c GP
041 0 $a eng
050 4 $a QD411 $b .O743 2019
072 7 $a PNRD $2 bicssc
072 7 $a SCI013060 $2 bisacsh
072 7 $a PNRD $2 thema
082 0 4 $a 661.895 $2 23
090 $a QD411 $b .O68 2019
245 0 0 $a Organometallics for green catalysis $h [electronic resource] / $c edited by Pierre H. Dixneuf, Jean-Francois Soule.
260 $a Cham : $b Springer International Publishing : $b Imprint: Springer, $c 2019.
300 $a x, 301 p. : $b ill., digital ; $c 24 cm.
490 1 $a Topics in organometallic chemistry, $x 1436-6002 ; $v 63
505 0 $a Metal-Catalysed Hydrogenation of CO2 into Methanol -- Catalytic C-C Bond Formations from CO2 with Alkenes -- Recent advances on CO2 utilization as C1 building block in C-N and C-O bond formation -- "Alkene Metathesis for Transformation of Renewables" -- Metal-Catalyzed Aromatic C-O Bond Activation/Transformation -- Hydrogenation/Dehydrogenation of Unsaturated Bonds with Iron Pincer Catalysis -- Conversion of Alcohols to Carboxylates Using Water and Base with H2 Liberation -- Selective Transfer-hydrogenation of α,β-Unsaturated Carbonyl Compounds -- Functionalization of C(sp2)-H Bonds of Arenes and Heteroarenes Assisted by Photoredox-Catalysts for the C-C Bond Formation -- Green Cross-Coupling using Visible-light for C-O and C-N Bond Formation.
520 $a This volume presents the latest developments in the use of organometallic catalysis for the formation of bulk chemicals and the production of energy, via green processes including efficient utilization of waste feedstocks from industry. The chemistry of carbon dioxide relating to its hydrogenation into methanol -an eco-friendly energy storage strategy- and its uses as C1 synthon for the formation of important building-blocks for fine chemicals industry are covered. Catalytic hydrogenations of various functional groups and hydrogen transfer reactions including the use of first row metal catalysts are presented as well as the conversion of alcohols to carboxylates via hydrogen transfer with a zero-waste strategy using water. Transformation of renewable or bio-based raw materials is surveyed through alkene metathesis and C-O bond activations and functionalizations. A green aspect for selective formation of C-C, C-O and C-N bonds involves direct regioselective C-H bond activations and functionalizations. These transformations can now be promoted under mild reaction conditions due to the use photoredox catalyts. C-H bond oxidation using visible light leads mainly to the formation of C-O and C-N bonds, whereas cross-coupled C-C bonds can be formed through the radical additions on (hetero) arenes using photoredox assisted mechanism.
650 0 $a Organometallic compounds. $3 224541
650 0 $a Green chemistry. $3 676886
650 1 4 $a Catalysis. $3 188259
650 2 4 $a Green Chemistry. $3 785187
650 2 4 $a Organometallic Chemistry. $3 275305
650 2 4 $a Industrial Chemistry/Chemical Engineering. $3 273974
700 1 $a Dixneuf, Pierre H. $3 701594
700 1 $a Soule, Jean-Francois. $3 834993
710 2 $a SpringerLink (Online service) $3 273601
773 0 $t Springer eBooks
830 0 $a Topics in organometallic chemistry ; $v 38 $3 558000
856 4 0 $u https://doi.org/10.1007/978-3-030-10955-4
950 $a Chemistry and Materials Science (Springer-11644)