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Metallo-supramolecular polymerssynth...

Higuchi, Masayoshi.

Metallo-supramolecular polymerssynthesis, properties, and device applications /

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Metallo-supramolecular polymersby Masayoshi Higuchi.
其他題名:	synthesis, properties, and device applications /
作者:	Higuchi, Masayoshi.
出版者:	Tokyo :Springer Japan :2019.
面頁冊數:	ix, 89 p. :ill., digital ;24 cm.
Contained By:	Springer eBooks
標題:	Polymers.
電子資源:	https://doi.org/10.1007/978-4-431-56891-9
ISBN:	9784431568919$q(electronic bk.)

Metallo-supramolecular polymerssynthesis, properties, and device applications /
Higuchi, Masayoshi.

Metallo-supramolecular polymerssynthesis, properties, and device applications /[electronic resource] :by Masayoshi Higuchi. - Tokyo :Springer Japan :2019. - ix, 89 p. :ill., digital ;24 cm. - NIMS monographs,2197-8891. - NIMS monographs..

Introduction -- Fe(II)-based metallo-supramolecular polymers -- Ru(II)-based metallo-supramolecular polymers -- Co(II)-based metallo-supramolecular polymers -- Zn(II)-based metallo-supramolecular polymers -- Cu(II)-based metallo-supramolecular polymers -- Pt(II)-based metallo-supramolecular polymers -- Ni(II)-based metallo-supramolecular polymers -- Mo(VI)-based metallo-supramolecular polymer -- Cd(II)-based metallo-supramolecular polymer -- Eu(III)-based metallo-supramolecular polymer -- Summary.

This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II) The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.

ISBN: 9784431568919$q(electronic bk.)

Standard No.: 10.1007/978-4-431-56891-9doiSubjects--Topical Terms:

188330
Polymers.

LC Class. No.: QD381 / .H548 2019

Dewey Class. No.: 620.192

Metallo-supramolecular polymerssynthesis, properties, and device applications /
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520 $a This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II) The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.
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