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Metallo-supramolecular polymerssynth...

Higuchi, Masayoshi.

Metallo-supramolecular polymerssynthesis, properties, and device applications /

Record Type:	Electronic resources : Monograph/item
Title/Author:	Metallo-supramolecular polymersby Masayoshi Higuchi.
Reminder of title:	synthesis, properties, and device applications /
Author:	Higuchi, Masayoshi.
Published:	Tokyo :Springer Japan :2019.
Description:	ix, 89 p. :ill., digital ;24 cm.
Contained By:	Springer eBooks
Subject:	Polymers.
Online resource:	https://doi.org/10.1007/978-4-431-56891-9
ISBN:	9784431568919$q(electronic bk.)

Metallo-supramolecular polymerssynthesis, properties, and device applications /
Higuchi, Masayoshi.

Metallo-supramolecular polymerssynthesis, properties, and device applications /[electronic resource] :by Masayoshi Higuchi. - Tokyo :Springer Japan :2019. - ix, 89 p. :ill., digital ;24 cm. - NIMS monographs,2197-8891. - NIMS monographs..

Introduction -- Fe(II)-based metallo-supramolecular polymers -- Ru(II)-based metallo-supramolecular polymers -- Co(II)-based metallo-supramolecular polymers -- Zn(II)-based metallo-supramolecular polymers -- Cu(II)-based metallo-supramolecular polymers -- Pt(II)-based metallo-supramolecular polymers -- Ni(II)-based metallo-supramolecular polymers -- Mo(VI)-based metallo-supramolecular polymer -- Cd(II)-based metallo-supramolecular polymer -- Eu(III)-based metallo-supramolecular polymer -- Summary.

This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II) The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.

ISBN: 9784431568919$q(electronic bk.)

Standard No.: 10.1007/978-4-431-56891-9doiSubjects--Topical Terms:

188330
Polymers.

LC Class. No.: QD381 / .H548 2019

Dewey Class. No.: 620.192

Metallo-supramolecular polymerssynthesis, properties, and device applications /
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245 1 0 $a Metallo-supramolecular polymers $h [electronic resource] : $b synthesis, properties, and device applications / $c by Masayoshi Higuchi.
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505 0 $a Introduction -- Fe(II)-based metallo-supramolecular polymers -- Ru(II)-based metallo-supramolecular polymers -- Co(II)-based metallo-supramolecular polymers -- Zn(II)-based metallo-supramolecular polymers -- Cu(II)-based metallo-supramolecular polymers -- Pt(II)-based metallo-supramolecular polymers -- Ni(II)-based metallo-supramolecular polymers -- Mo(VI)-based metallo-supramolecular polymer -- Cd(II)-based metallo-supramolecular polymer -- Eu(III)-based metallo-supramolecular polymer -- Summary.
520 $a This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II) The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.
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