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Manipulation of matrix-isolated mole...

Park, Youngwook.

Manipulation of matrix-isolated molecules and molecular clusters with electrostatic fields

Record Type:	Electronic resources : Monograph/item
Title/Author:	Manipulation of matrix-isolated molecules and molecular clusters with electrostatic fieldsby Youngwook Park.
Author:	Park, Youngwook.
Published:	Singapore :Springer Singapore :2020.
Description:	xvi, 41 p. :ill., digital ;24 cm.
Contained By:	Springer Nature eBook
Subject:	Matrix isolation spectroscopy.
Online resource:	https://doi.org/10.1007/978-981-15-8693-4
ISBN:	9789811586934$q(electronic bk.)

Manipulation of matrix-isolated molecules and molecular clusters with electrostatic fields
Park, Youngwook.

Manipulation of matrix-isolated molecules and molecular clusters with electrostatic fields[electronic resource] /by Youngwook Park. - Singapore :Springer Singapore :2020. - xvi, 41 p. :ill., digital ;24 cm. - Springer theses,2190-5053. - Springer theses..

Introduction -- Method -- Electric Field-Control of Inversion Dynamics of Ammonia in an Argon Matrix -- Spectroscopic Evidence of Large Protonic Polarizability of Hydrogen Chloride-Water Complexes -- Summary.

This book describes the manipulation of molecular properties, such as orientation, structure, and dynamics, of small molecules and molecular clusters isolated in cold inert matrices by using unprecedentedly strong external electrostatic fields. Manipulation of molecules with controllable external forces is a dream of chemists. Molecules are inherently quantum-mechanical systems, control of which potentially can lead to quantum technology, such as quantum sensing and computing. This book demonstrates a combination of the ice film nanocapacitor method and the matrix isolation technique enabled the application of intense external dc electric fields across the isolated molecules and molecular clusters. Changes in molecular states induced by fields were monitored by means of vibrational spectroscopy. Also, the book presents manipulations of the inversion tunneling dynamics of ammonia molecule and the dislocation of acidic proton in hydrogen chloride-water complex. The book shows that the vibrational spectroscopy with the aid of unprecedentedly strong dc electric field can provide rich information on the electrostatic behaviors of molecules and molecular clusters, which underlie the understanding of intermolecular processes and molecular manipulation.

ISBN: 9789811586934$q(electronic bk.)

Standard No.: 10.1007/978-981-15-8693-4doiSubjects--Topical Terms:

877770
Matrix isolation spectroscopy.

LC Class. No.: QC454.M32 / P375 2020

Dewey Class. No.: 543.54

Manipulation of matrix-isolated molecules and molecular clusters with electrostatic fields
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520 $a This book describes the manipulation of molecular properties, such as orientation, structure, and dynamics, of small molecules and molecular clusters isolated in cold inert matrices by using unprecedentedly strong external electrostatic fields. Manipulation of molecules with controllable external forces is a dream of chemists. Molecules are inherently quantum-mechanical systems, control of which potentially can lead to quantum technology, such as quantum sensing and computing. This book demonstrates a combination of the ice film nanocapacitor method and the matrix isolation technique enabled the application of intense external dc electric fields across the isolated molecules and molecular clusters. Changes in molecular states induced by fields were monitored by means of vibrational spectroscopy. Also, the book presents manipulations of the inversion tunneling dynamics of ammonia molecule and the dislocation of acidic proton in hydrogen chloride-water complex. The book shows that the vibrational spectroscopy with the aid of unprecedentedly strong dc electric field can provide rich information on the electrostatic behaviors of molecules and molecular clusters, which underlie the understanding of intermolecular processes and molecular manipulation.
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