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Metal-ligand co-operativitycatalysis...

Kirchner, Karl.

Metal-ligand co-operativitycatalysis and the pincer-metal platform /

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Metal-ligand co-operativityedited by Gerard van Koten, Karl Kirchner, Marc-Etienne Moret.
其他題名:	catalysis and the pincer-metal platform /
其他作者:	Koten, Gerard van.
出版者:	Cham :Springer International Publishing :2021.
面頁冊數:	x, 451 p. :ill., digital ;24 cm.
Contained By:	Springer Nature eBook
標題:	Ligands (Biochemistry)
電子資源:	https://doi.org/10.1007/978-3-030-68916-2
ISBN:	9783030689162$q(electronic bk.)

Metal-ligand co-operativitycatalysis and the pincer-metal platform /
Metal-ligand co-operativitycatalysis and the pincer-metal platform /[electronic resource] :edited by Gerard van Koten, Karl Kirchner, Marc-Etienne Moret. - Cham :Springer International Publishing :2021. - x, 451 p. :ill., digital ;24 cm. - Topics in organometallic chemistry,681436-6002 ;. - Topics in organometallic chemistry ;38.

Recent Advances in the Applications of Metal-Ligand Cooperation via Dearomatization and Aromatization of Pincer Complexes -- Metal-Ligand Cooperation at Acceptor Pincer ligands -- Metal-Ligand Cooperativity of Phosphorus Containing Pincer Systems -- Cooperative Reactivity by Pincer-type Complexes Possessing Secondary Coordination Sphere -- Redox-Active Pincer Ligands -- A Pincer Motif Etched into a meta-Benziporphyrin Frame -- The role of Metal-Ligand Cooperation in Manganese(I)-catalyzed Hydrogenation/Dehydrogenation Reactions -- Hydrogenation Reactions Catalyzed by PNP-Type Complexes featuring a HN(CH2CH2PR2)2 Ligand -- Catalytic Conversion of Nitriles by Metal Pincer Complexes -- The Application of Pincer Ligand in Catalytic Water Splitting.

This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M-L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns.

ISBN: 9783030689162$q(electronic bk.)

Standard No.: 10.1007/978-3-030-68916-2doiSubjects--Topical Terms:

339326
Ligands (Biochemistry)

LC Class. No.: QD474

Dewey Class. No.: 541.2242

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520 $a This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M-L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns.
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