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Design of electronic devices using r...

Kim, Jaejun.

Design of electronic devices using redox-active organic molecules and their porous coordination networks

Record Type:	Electronic resources : Monograph/item
Title/Author:	Design of electronic devices using redox-active organic molecules and their porous coordination networksby Jaejun Kim.
Author:	Kim, Jaejun.
Published:	Singapore :Springer Singapore :2021.
Description:	xiv, 76 p. :ill., digital ;24 cm.
Contained By:	Springer Nature eBook
Subject:	Organic electronicsDesign and construction.
Online resource:	https://doi.org/10.1007/978-981-16-3907-4
ISBN:	9789811639074

Design of electronic devices using redox-active organic molecules and their porous coordination networks
Kim, Jaejun.

Design of electronic devices using redox-active organic molecules and their porous coordination networks[electronic resource] /by Jaejun Kim. - Singapore :Springer Singapore :2021. - xiv, 76 p. :ill., digital ;24 cm. - Springer theses,2190-5061. - Springer theses..

1. General Introduction -- 2. Resistive Switching Memory Devices Based on a Redox-active Organic Molecule -- 3. Humidity Detection Based on Redox-active Porous Coordination Networks -- 4. Tunable Electrical Properties of Redox-active Porous Coordination Networks via Post-synthetic Modification -- 5. Summary and Outlook.

This book addresses the development of electronic devices using redox-active organic molecules and their porous coordination networks (PCNs), and highlights the importance of the molecular arrangement. Redox-active organic molecules hold considerable promise as flexible electronic elements, because their electronic state can easily be controlled using external energy. Although various kinds of redox-active organic molecules have been synthesized, attempts to apply them to electronic devices have been limited, owing to the lack of proper structural design. Moreover, ligand-based redox-active PCNs remain largely unexplored because of the limited availability of redox-active ligands. In addition to developing new redox-active organic molecules, in order to design electronic devices based on these molecules/PCNs, it is essential to understand the connections between their molecular arrangement, electrical properties, and redox activity. In this thesis, the redox-active organic molecule 2,5,8-tri(4-pyridyl)1,3-diazaphenalene (TPDAP), which features a large pi plane and multi-intermolecular interactivity, is used to develop a resistive switching memory device. In addition, its PCNs are synthesized to fabricate chemiresistive sensors, and the electrical properties are modulated using post-synthetic modification. Each mechanism is systematically investigated by means of structural determination and well-defined control experiments. Subsequently, the book proposes general guidelines for designing electronic devices using redox-active organic molecules. The book will appeal to a broad range of readers, from basic scientists to materials engineers, as well as general, non-expert readers.

ISBN: 9789811639074

Standard No.: 10.1007/978-981-16-3907-4doiSubjects--Topical Terms:

904955
Organic electronics
--Design and construction.

LC Class. No.: QC611.8.O7

Dewey Class. No.: 621.381

Design of electronic devices using redox-active organic molecules and their porous coordination networks
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520 $a This book addresses the development of electronic devices using redox-active organic molecules and their porous coordination networks (PCNs), and highlights the importance of the molecular arrangement. Redox-active organic molecules hold considerable promise as flexible electronic elements, because their electronic state can easily be controlled using external energy. Although various kinds of redox-active organic molecules have been synthesized, attempts to apply them to electronic devices have been limited, owing to the lack of proper structural design. Moreover, ligand-based redox-active PCNs remain largely unexplored because of the limited availability of redox-active ligands. In addition to developing new redox-active organic molecules, in order to design electronic devices based on these molecules/PCNs, it is essential to understand the connections between their molecular arrangement, electrical properties, and redox activity. In this thesis, the redox-active organic molecule 2,5,8-tri(4-pyridyl)1,3-diazaphenalene (TPDAP), which features a large pi plane and multi-intermolecular interactivity, is used to develop a resistive switching memory device. In addition, its PCNs are synthesized to fabricate chemiresistive sensors, and the electrical properties are modulated using post-synthetic modification. Each mechanism is systematically investigated by means of structural determination and well-defined control experiments. Subsequently, the book proposes general guidelines for designing electronic devices using redox-active organic molecules. The book will appeal to a broad range of readers, from basic scientists to materials engineers, as well as general, non-expert readers.
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