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Microwave Synthesis and Photophysical Characterization of Heteroleptic Iridium Complexes for Applications in OLEDs and OLEDs.

Record Type:	Electronic resources : Monographic component part
Title/Author:	Microwave Synthesis and Photophysical Characterization of Heteroleptic Iridium Complexes for Applications in OLEDs and OLEDs.
Author:	Dixon, Allyson.
Published:	Ann Arbor : ProQuest Dissertations & Theses, 2023
Description:	129 p.
Notes:	Source: Dissertations Abstracts International, Volume: 84-11, Section: B.
Notes:	Advisor: Murphy, Wyatt R., Jr.
Contained By:	Dissertations Abstracts International84-11B.
Subject:	Chemistry.
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30491748
ISBN:	9798379520304

Microwave Synthesis and Photophysical Characterization of Heteroleptic Iridium Complexes for Applications in OLEDs and OLEDs.
Dixon, Allyson.

Microwave Synthesis and Photophysical Characterization of Heteroleptic Iridium Complexes for Applications in OLEDs and OLEDs. - Ann Arbor : ProQuest Dissertations & Theses, 2023 - 129 p.

Source: Dissertations Abstracts International, Volume: 84-11, Section: B.

Thesis (Ph.D.)--Seton Hall University, 2023.

This item must not be sold to any third party vendors.

A series of heteroleptic, iridium-based ionic transition metal complexes (ir-iTMCS), with the purpose to serve as potential components of OLED and LEC devices, were synthesized through a green, combinatorial-based approach. This work utilized a microwave reactor in order to bring our research into closer alignment with the tenets of green chemistry. The aim of this research was to assess the effects of structural differences, specifically steric crowding, on the photophysical characteristics of the complexes. The radiative quantum efficiencies (Φf) and excited state lifetimes (τ ) of the series of Ir-iTMCs were investigated. The rates of radiative (kr) and nonradiative decay (knr) were calculated and yielded interesting results; the energy gap law was not followed. Of the eight Ir-iTMCs, two complexes exhibited quantum efficiencies close to 100% and lifetimes within the desirable range for applications in OLEDs and LECs. The rate of radiative decay was larger than that of the nonradiative decay for the two complexes of interest. As a result, the focus should be shifted onto kr as opposed to knr for highly efficient Ir-iTMCs with applications in OLEDs and LECs.

ISBN: 9798379520304Subjects--Topical Terms:

188628
Chemistry.
Subjects--Index Terms:

Cuproines

Microwave Synthesis and Photophysical Characterization of Heteroleptic Iridium Complexes for Applications in OLEDs and OLEDs.
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100 1 $a Dixon, Allyson. $0 (orcid)0000-0001-7949-1305 $3 966854
245 1 0 $a Microwave Synthesis and Photophysical Characterization of Heteroleptic Iridium Complexes for Applications in OLEDs and OLEDs.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2023
300 $a 129 p.
500 $a Source: Dissertations Abstracts International, Volume: 84-11, Section: B.
500 $a Advisor: Murphy, Wyatt R., Jr.
502 $a Thesis (Ph.D.)--Seton Hall University, 2023.
506 $a This item must not be sold to any third party vendors.
520 $a A series of heteroleptic, iridium-based ionic transition metal complexes (ir-iTMCS), with the purpose to serve as potential components of OLED and LEC devices, were synthesized through a green, combinatorial-based approach. This work utilized a microwave reactor in order to bring our research into closer alignment with the tenets of green chemistry. The aim of this research was to assess the effects of structural differences, specifically steric crowding, on the photophysical characteristics of the complexes. The radiative quantum efficiencies (Φf) and excited state lifetimes (τ ) of the series of Ir-iTMCs were investigated. The rates of radiative (kr) and nonradiative decay (knr) were calculated and yielded interesting results; the energy gap law was not followed. Of the eight Ir-iTMCs, two complexes exhibited quantum efficiencies close to 100% and lifetimes within the desirable range for applications in OLEDs and LECs. The rate of radiative decay was larger than that of the nonradiative decay for the two complexes of interest. As a result, the focus should be shifted onto kr as opposed to knr for highly efficient Ir-iTMCs with applications in OLEDs and LECs.
590 $a School code: 0199.
650 4 $a Chemistry. $3 188628
650 4 $a Inorganic chemistry. $3 708705
650 4 $a Biochemistry. $3 188609
653 $a Cuproines
653 $a Green chemistry
653 $a Iridium (III) complexes
653 $a Microwave-assisted synthesis
653 $a Organic Light Emitting Devices
690 $a 0485
690 $a 0488
690 $a 0487
710 2 $a Seton Hall University. $b Chemistry. $3 966855
773 0 $t Dissertations Abstracts International $g 84-11B.
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791 $a Ph.D.
792 $a 2023
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30491748