國立高雄大學圖資館 |

Language: English

Back

Supramolecular complexes of oxoporphyrinogens with organic molecules

Record Type:	Electronic resources : Monograph/item
Title/Author:	Supramolecular complexes of oxoporphyrinogens with organic moleculesby Václav Březina.
Author:	Březina, Václav.
Published:	Cham :Springer Nature Switzerland :2024.
Description:	xv, 214 p. :ill., digital ;24 cm.
Notes:	"Doctoral thesis accepted by Charles University, Prague, Czech Republic."
Contained By:	Springer Nature eBook
Subject:	Supramolecular chemistry.
Online resource:	https://doi.org/10.1007/978-3-031-68646-7
ISBN:	9783031686467$q(electronic bk.)

Supramolecular complexes of oxoporphyrinogens with organic molecules
Březina, Václav.

Supramolecular complexes of oxoporphyrinogens with organic molecules[electronic resource] /by Václav Březina. - Cham :Springer Nature Switzerland :2024. - xv, 214 p. :ill., digital ;24 cm. - Springer theses,2190-5061. - Springer theses..

"Doctoral thesis accepted by Charles University, Prague, Czech Republic."

Introduction -- Quantitative description ofsupramolecular binding -- Nuclear magnetic resonancespectroscopy -- UV/vis spectroscopy -- Singular value decomposition -- Chromic and binding propertiesof OxP derivatives -- Dynamic processes and chemicalexchange in OxP derivatives -- Conclusion.

Macrocyclic oxoporphyrinogen molecules combine the ability to form strong supramolecular complexes with organic compounds and the ability to absorb light. These properties allow high-sensitivity colorimetric detection of acids in solution in the presence of oxoporphyrinogen. Moreover, protonated oxoporphyrinogens show various molecular dynamic processes on the millisecond timescale. This book offers deep analyses of colorimetric, binding and kinetic properties of oxoporphyrinogen-acid complexes. A detailed introduction is given for: theory of supramolecular binding and chemical kinetics; NMR spectroscopy with emphasis on multi-state chemical exchange including derivation of analytical spectral lineshapes; UV/vis spectroscopy and analysis of UV/vis spectra, using singular value decomposition (SVD). Implementation of the derived models in Mathematica is also provided. The experimental part addresses SVD analysis of UV/vis spectra illuminating the effect of protonation on various oxoporphyrinogen derivatives and explaining the colorimetric response. Furthermore, analysis of chemical exchange lineshapes offers insight into the dynamic processes present in protonated oxoporphyrinogens. The various models and techniques described in this book are widely applicable for other systems.

ISBN: 9783031686467$q(electronic bk.)

Standard No.: 10.1007/978-3-031-68646-7doiSubjects--Topical Terms:

224270
Supramolecular chemistry.

LC Class. No.: QD878

Dewey Class. No.: 547.1226

Supramolecular complexes of oxoporphyrinogens with organic molecules
LDR:02704nmm a2200349 a 4500 001 673661
003 DE-He213
005 20250104115224.0
006 m d
007 cr nn 008maaau
008 250422s2024 sz s 0 eng d
020 $a 9783031686467$q(electronic bk.)
020 $a 9783031686450$q(paper)
024 7 $a 10.1007/978-3-031-68646-7 $2 doi
035 $a 978-3-031-68646-7
040 $a GP $c GP
041 0 $a eng
050 4 $a QD878
072 7 $a PHM $2 bicssc
072 7 $a SCI074000 $2 bisacsh
072 7 $a PHM $2 thema
082 0 4 $a 547.1226 $2 23
090 $a QD878 $b .B848 2024
100 1 $a Březina, Václav. $3 987226
245 1 0 $a Supramolecular complexes of oxoporphyrinogens with organic molecules $h [electronic resource] / $c by Václav Březina.
260 $a Cham : $b Springer Nature Switzerland : $b Imprint: Springer, $c 2024.
300 $a xv, 214 p. : $b ill., digital ; $c 24 cm.
490 1 $a Springer theses, $x 2190-5061
500 $a "Doctoral thesis accepted by Charles University, Prague, Czech Republic."
505 0 $a Introduction -- Quantitative description ofsupramolecular binding -- Nuclear magnetic resonancespectroscopy -- UV/vis spectroscopy -- Singular value decomposition -- Chromic and binding propertiesof OxP derivatives -- Dynamic processes and chemicalexchange in OxP derivatives -- Conclusion.
520 $a Macrocyclic oxoporphyrinogen molecules combine the ability to form strong supramolecular complexes with organic compounds and the ability to absorb light. These properties allow high-sensitivity colorimetric detection of acids in solution in the presence of oxoporphyrinogen. Moreover, protonated oxoporphyrinogens show various molecular dynamic processes on the millisecond timescale. This book offers deep analyses of colorimetric, binding and kinetic properties of oxoporphyrinogen-acid complexes. A detailed introduction is given for: theory of supramolecular binding and chemical kinetics; NMR spectroscopy with emphasis on multi-state chemical exchange including derivation of analytical spectral lineshapes; UV/vis spectroscopy and analysis of UV/vis spectra, using singular value decomposition (SVD). Implementation of the derived models in Mathematica is also provided. The experimental part addresses SVD analysis of UV/vis spectra illuminating the effect of protonation on various oxoporphyrinogen derivatives and explaining the colorimetric response. Furthermore, analysis of chemical exchange lineshapes offers insight into the dynamic processes present in protonated oxoporphyrinogens. The various models and techniques described in this book are widely applicable for other systems.
650 0 $a Supramolecular chemistry. $3 224270
650 0 $a Colorimetry. $3 220458
650 0 $a Nuclear magnetic resonance spectroscopy. $3 188585
650 1 4 $a Atomic, Molecular and Chemical Physics. $3 913484
650 2 4 $a Bio- and Macromolecules. $3 924064
650 2 4 $a Magnetic Resonance (NMR, EPR) $3 924051
650 2 4 $a Sensors. $3 915776
710 2 $a SpringerLink (Online service) $3 273601
773 0 $t Springer Nature eBook
830 0 $a Springer theses. $3 557607
856 4 0 $u https://doi.org/10.1007/978-3-031-68646-7
950 $a Physics and Astronomy (SpringerNature-11651)