國立高雄大學圖資館 |

Language: English

Back

Electronic structures and bonding interaction of structurally defined gold/silver superatomsprobed by anion photoelectron spectroscopy /

Record Type:	Electronic resources : Monograph/item
Title/Author:	Electronic structures and bonding interaction of structurally defined gold/silver superatomsby Shun Ito.
Reminder of title:	probed by anion photoelectron spectroscopy /
Author:	Ito, Shun.
Published:	Singapore :Springer Nature Singapore :2025.
Description:	xiii, 112 p. :ill., digital ;24 cm.
Notes:	"Doctoral thesis accepted by the University of Tokyo, Tokyo, Japan."
Contained By:	Springer Nature eBook
Subject:	Photoelectron spectroscopy.
Online resource:	https://doi.org/10.1007/978-981-96-2892-6
ISBN:	9789819628926$q(electronic bk.)

Electronic structures and bonding interaction of structurally defined gold/silver superatomsprobed by anion photoelectron spectroscopy /
Ito, Shun.

Electronic structures and bonding interaction of structurally defined gold/silver superatomsprobed by anion photoelectron spectroscopy /[electronic resource] :by Shun Ito. - Singapore :Springer Nature Singapore :2025. - xiii, 112 p. :ill., digital ;24 cm. - Springer theses, recognizing outstanding Ph.D. research,2190-5061. - Springer theses, recognizing outstanding Ph.D. research..

"Doctoral thesis accepted by the University of Tokyo, Tokyo, Japan."

Chapter 1.Introduction -- Chapter 2.Experimental Setup of Anion Photoelectron Spectroscopy -- Chapter 3.Effect of Heterometal Doping on Electron Affinities of Eight Electron Superatoms -- Chapter 4.Effect of Ligand Substitution on Electron Affinities of Eight Electron Superatoms -- Chapter 5.Bonding Interaction in Homonuclear Superatomic Molecules -- Chapter 6.Bonding Interaction in Heteronuclear Superatomic Molecules -- Chapter 7.Summary and prospects.

This book focuses on ligand-protected gold clusters featuring their atomically precise compositions and unambiguous structures. They mimic electronic shell structures of atoms and are called structurally defined superatoms. The book describes the design principle of superatomic electronic structures and the bonding theory of superatoms as revealed by gas-phase anion photoelectron spectroscopy, which is conducted by using a state-of-the-art home-built apparatus and sheds light on fundamental electronic structures such as density of states and electron affinities otherwise elusive. This study revealed that the energy level of superatomic orbitals can be tuned coarsely by the heterometal doping and finely by the stepwise ligand exchange, respectively. The bonding theory of superatoms was also developed by anion photoelectron spectroscopy of homonuclear and heteronuclear superatoms. The comprehensive review of superatoms and detailed explanation of the apparatus were described in addition to individual studies. This book provides design principles of structurally defined superatoms and stimulates future research on the chemical and physical properties of superatoms.

ISBN: 9789819628926$q(electronic bk.)

Standard No.: 10.1007/978-981-96-2892-6doiSubjects--Topical Terms:

663741
Photoelectron spectroscopy.

LC Class. No.: QC454.P48

Dewey Class. No.: 543.62

Electronic structures and bonding interaction of structurally defined gold/silver superatomsprobed by anion photoelectron spectroscopy /
LDR:02925nmm a2200373 a 4500 001 679471
003 DE-He213
005 20250314115245.0
006 m d
007 cr nn 008maaau
008 251110s2025 si s 0 eng d
020 $a 9789819628926$q(electronic bk.)
020 $a 9789819628919$q(paper)
024 7 $a 10.1007/978-981-96-2892-6 $2 doi
035 $a 978-981-96-2892-6
040 $a GP $c GP
041 0 $a eng
050 4 $a QC454.P48
072 7 $a TBN $2 bicssc
072 7 $a TGM $2 bicssc
072 7 $a SCI013050 $2 bisacsh
072 7 $a TBN $2 thema
072 7 $a PDT $2 thema
082 0 4 $a 543.62 $2 23
090 $a QC454.P48 $b I89 2025
100 1 $a Ito, Shun. $3 992421
245 1 0 $a Electronic structures and bonding interaction of structurally defined gold/silver superatoms $h [electronic resource] : $b probed by anion photoelectron spectroscopy / $c by Shun Ito.
260 $a Singapore : $b Springer Nature Singapore : $b Imprint: Springer, $c 2025.
300 $a xiii, 112 p. : $b ill., digital ; $c 24 cm.
490 1 $a Springer theses, recognizing outstanding Ph.D. research, $x 2190-5061
500 $a "Doctoral thesis accepted by the University of Tokyo, Tokyo, Japan."
505 0 $a Chapter 1.Introduction -- Chapter 2.Experimental Setup of Anion Photoelectron Spectroscopy -- Chapter 3.Effect of Heterometal Doping on Electron Affinities of Eight Electron Superatoms -- Chapter 4.Effect of Ligand Substitution on Electron Affinities of Eight Electron Superatoms -- Chapter 5.Bonding Interaction in Homonuclear Superatomic Molecules -- Chapter 6.Bonding Interaction in Heteronuclear Superatomic Molecules -- Chapter 7.Summary and prospects.
520 $a This book focuses on ligand-protected gold clusters featuring their atomically precise compositions and unambiguous structures. They mimic electronic shell structures of atoms and are called structurally defined superatoms. The book describes the design principle of superatomic electronic structures and the bonding theory of superatoms as revealed by gas-phase anion photoelectron spectroscopy, which is conducted by using a state-of-the-art home-built apparatus and sheds light on fundamental electronic structures such as density of states and electron affinities otherwise elusive. This study revealed that the energy level of superatomic orbitals can be tuned coarsely by the heterometal doping and finely by the stepwise ligand exchange, respectively. The bonding theory of superatoms was also developed by anion photoelectron spectroscopy of homonuclear and heteronuclear superatoms. The comprehensive review of superatoms and detailed explanation of the apparatus were described in addition to individual studies. This book provides design principles of structurally defined superatoms and stimulates future research on the chemical and physical properties of superatoms.
650 0 $a Photoelectron spectroscopy. $3 663741
650 0 $a lectronic structure. $3 992422
650 0 $a Nanostructured materials. $3 216041
650 0 $a Gold. $3 218914
650 0 $a Silver. $3 714012
650 1 4 $a Nanochemistry. $3 264782
650 2 4 $a Spectroscopy. $3 737192
650 2 4 $a Density Functional Theory. $3 944056
650 2 4 $a Nanoparticles. $3 210980
710 2 $a SpringerLink (Online service) $3 273601
773 0 $t Springer Nature eBook
830 0 $a Springer theses, recognizing outstanding Ph.D. research. $3 563311
856 4 0 $u https://doi.org/10.1007/978-981-96-2892-6
950 $a Chemistry and Materials Science (SpringerNature-11644)