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Controlling the work function of indium tin oxide with organometallic surface complexes.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Controlling the work function of indium tin oxide with organometallic surface complexes.
作者:	Bruner, Eric Lawrence.
面頁冊數:	128 p.
附註:	Source: Dissertation Abstracts International, Volume: 63-10, Section: B, page: 4645.
Contained By:	Dissertation Abstracts International63-10B.
標題:	Chemistry, General.
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3068785
ISBN:	0493884319

Controlling the work function of indium tin oxide with organometallic surface complexes.
Bruner, Eric Lawrence.

Controlling the work function of indium tin oxide with organometallic surface complexes. [electronic resource] - 128 p.

Source: Dissertation Abstracts International, Volume: 63-10, Section: B, page: 4645.

Thesis (Ph.D.)--Princeton University, 2003.

The reactions of tetra(tert-butoxy)tin and tetrakis(diethylamino)tin with indium in oxide (ITO) give surface-bound tin alkoxide and tin amide complexes respectively. Organic acids with appropriate acidities initiate ligand metathesis with these surface complexes. Surface bound (arylacetylide)tin and (phenoxide)tin species were synthesized in ultra-high vacuum and characterized by X-ray photoelectron spectroscopy, mass spectrometry, and reflective absorption infrared spectroscopy. A series of substituted phenols, with a range of dipole moments and acidities, was reacted with surface-bound tin alkoxide to probe the validity of a dipole-moment model. The use of o- and p-substituted phenoxytin surface complexes demonstrated that dipolar properties of the surface bound species, and not local electronegativity effects, control the work function of ITO.

ISBN: 0493884319Subjects--Topical Terms:

226910
Chemistry, General.

Controlling the work function of indium tin oxide with organometallic surface complexes.
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