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電洞材料在固態染料敏化太陽能電池的比較研究 = Fabrication ...

國立高雄大學化學工程及材料工程學系碩士班

電洞材料在固態染料敏化太陽能電池的比較研究 = Fabrication of Solid-state Dyes-sensitized Solar cells

Record Type:	Language materials, printed : monographic
Paralel Title:	Fabrication of Solid-state Dyes-sensitized Solar cells
Author:	黃琮勝,
Secondary Intellectual Responsibility:	國立高雄大學
Place of Publication:	[高雄市]
Published:	撰者;
Year of Publication:	2014[民103]
Description:	89面圖，表 : 30公分;
Subject:	鈣鈦礦染料，CH3NH3PbI3，甲胺鉛碘，固態染料敏化太陽能電池
Subject:	Pervoskite dye
Online resource:	http://handle.ncl.edu.tw/11296/ndltd/50273921123230094551
Notes:	參考書目：面77-79
Notes:	103年12月16日公開
Summary:	在過去以液態電解質做為染料敏化太陽能電池的研究最為成熟，但液態電解質卻有容易揮發、洩液及常使用有毒溶劑…等缺點。為了解決液態電解質的問題本研究主要以 Methanaminium lead(II) iodide (CH3NH3PbI3) 作為固態染料敏化太陽能電池的染料，CH3NH3PbI3是一種鈣鈦礦系的染料，CH3NH3PbI3 相較於目前常見的釕金屬錯合物或全有機染料有低成本、低耗能、製作簡單…等優點。而在電洞輸送材料部分，因為市售的 Spiro-MeOTAD 價格不斐，自製了4-hexadecany-1-methylimidazolium iodide (C16MImI) 與4-(hexyloxy)-N,N-diphenylaniline (HDPA) 做為電動輸送材料並比較市售的聚(3-己基吩)( poly(3-hexylthiophene)，P3HT) 做為電洞輸送材料的效率，以P3HT做為電動輸送材料時，最佳光電轉換效率可達1.628 % ；另外以自製的C16MImI 和PHDPA做為電動輸送材料時，其最佳光電轉換效率分別為0.370 % 與0.140 %。 Over the past several years, the Dye-sensitized Solar Cells (DSSCs) are mainly studied by using liquid electrolytes in the devices. Liquid electrolytes are easy to leak or run off in the DSSC devices , whilst the components of these liquid electrolytes are seriously poisonous. In this work , we aim to solve this limitation of applications employing a solid-state hole transport material instead of liquid electrolytes in the DSSC devices.A Perovskite-based dye (methylammonium lead(II) iodide, CH3NH3PbI3) was prepared and used in the study. A series of the solid-state hole transport materials, conducting polymers (Poly(3-hexylthiophene)(P3HT)) and (Poly(4-(hexyloxy)-N,N-diphenylaniline (PHDPA)) and solid-state ionic liquid (4-hexadecany-1-methylimidazolium iodide (C16MImI)) , are assembled in the solid-state DSSCs. This kind of DSSC devices are tried to fabricate and studied the photo-electronic properties and device performance.

電洞材料在固態染料敏化太陽能電池的比較研究 = Fabrication of Solid-state Dyes-sensitized Solar cells
黃, 琮勝

電洞材料在固態染料敏化太陽能電池的比較研究 = Fabrication of Solid-state Dyes-sensitized Solar cells / 黃琮勝撰 - [高雄市] : 撰者, 2014[民103]. - 89面 ; 圖，表 ; 30公分.
參考書目：面77-79103年12月16日公開.
鈣鈦礦染料，CH3NH3PbI3，甲胺鉛碘，固態染料敏化太陽能電池Pervoskite dye

電洞材料在固態染料敏化太陽能電池的比較研究 = Fabrication of Solid-state Dyes-sensitized Solar cells
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314 $a 指導教授：楊乾信博士
328 $a 碩士論文--國立高雄大學化學工程及材料工程學系碩士班
330 $a 在過去以液態電解質做為染料敏化太陽能電池的研究最為成熟，但液態電解質卻有容易揮發、洩液及常使用有毒溶劑…等缺點。為了解決液態電解質的問題本研究主要以 Methanaminium lead(II) iodide (CH3NH3PbI3) 作為固態染料敏化太陽能電池的染料，CH3NH3PbI3是一種鈣鈦礦系的染料，CH3NH3PbI3 相較於目前常見的釕金屬錯合物或全有機染料有低成本、低耗能、製作簡單…等優點。而在電洞輸送材料部分，因為市售的 Spiro-MeOTAD 價格不斐，自製了4-hexadecany-1-methylimidazolium iodide (C16MImI) 與4-(hexyloxy)-N,N-diphenylaniline (HDPA) 做為電動輸送材料並比較市售的聚(3-己基吩)( poly(3-hexylthiophene)，P3HT) 做為電洞輸送材料的效率，以P3HT做為電動輸送材料時，最佳光電轉換效率可達1.628 % ；另外以自製的C16MImI 和PHDPA做為電動輸送材料時，其最佳光電轉換效率分別為0.370 % 與0.140 %。 Over the past several years, the Dye-sensitized Solar Cells (DSSCs) are mainly studied by using liquid electrolytes in the devices. Liquid electrolytes are easy to leak or run off in the DSSC devices , whilst the components of these liquid electrolytes are seriously poisonous. In this work , we aim to solve this limitation of applications employing a solid-state hole transport material instead of liquid electrolytes in the DSSC devices.A Perovskite-based dye (methylammonium lead(II) iodide, CH3NH3PbI3) was prepared and used in the study. A series of the solid-state hole transport materials, conducting polymers (Poly(3-hexylthiophene)(P3HT)) and (Poly(4-(hexyloxy)-N,N-diphenylaniline (PHDPA)) and solid-state ionic liquid (4-hexadecany-1-methylimidazolium iodide (C16MImI)) , are assembled in the solid-state DSSCs. This kind of DSSC devices are tried to fabricate and studied the photo-electronic properties and device performance.
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610 1 $a Pervoskite dye $a Methylammonium lead(II) iodide $a Solid-state dyes-sensitized solar cells
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